三氯氢硅

【用途一】
用作高分子有机硅化合物的原料，也用于仪表工业
【用途二】
制造有机硅化合物的原料，也是生产多晶硅的基本原料。

[ 密度 ]:
1.342 g/mL at 25 °C(lit.)

[ 沸点 ]:
31.8±9.0 °C at 760 mmHg

[ 熔点 ]:
-127 °C

[ 分子式 ]:
Cl₃HSi

[ 分子量 ]:
135.452

[ 闪点 ]:
7 °F

[ 精确质量 ]:
133.891312

[ LogP ]:
4.77

[ 外观性状 ]:
液体

[ 蒸汽密度 ]:
1 (vs air)

[ 蒸汽压 ]:
595.7±0.1 mmHg at 25°C

[ 折射率 ]:
1.4-1.402

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 稳定性 ]:
Stable, but extremely flammable. Pyrophoric - spontaneously ignites in air. Explosion hazard in air - note wide explosion limits. Reacts violently with water. Incompatible with moisture, acids, bases, strong oxidizing agents, alcohols, amines.

[ 水溶解性 ]:
decomposes

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

VV5950000

CHEMICAL NAME :

Silane, trichloro-

CAS REGISTRY NUMBER :

10025-78-2

LAST UPDATED :

199710

DATA ITEMS CITED :

7

MOLECULAR FORMULA :

Cl3-H-Si

MOLECULAR WEIGHT :

135.45

WISWESSER LINE NOTATION :

G-SI-HGG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

1030 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949

TYPE OF TEST :

LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

500 ppm/4H

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 2/21/1979

TYPE OF TEST :

LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

1500 mg/m3/2H

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,114,1982

TYPE OF TEST :

LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Mammal - species unspecified

DOSE/DURATION :

1 gm/m3

TOXIC EFFECTS :

Lungs, Thorax, or Respiration - acute pulmonary edema Liver - fatty liver degeneration Blood - other changes

REFERENCE :

TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 3,81,1961 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X3556 No. of Facilities: 23 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 2201 (estimated) No. of Female Employees: 267 (estimated)

[ 符号 ]:

GHS02, GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H224-H250-H302 + H332-H314

[ 补充危害声明 ]:
Contact with water liberates toxic gas., Reacts violently with water.

[ 警示性声明 ]:
P210-P280-P303 + P361 + P353-P305 + P351 + P338-P370 + P378-P422

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
F+:Highlyflammable;C:Corrosive;

[ 风险声明 (欧洲) ]:
R12;R14;R17;R20/22;R29;R35

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S43-S45-S7/9-S43A

[ 危险品运输编码 ]:
UN 1295 4.3/PG 1

[ WGK德国 ]:
1

[ RTECS号 ]:
VV5950000

[ 包装等级 ]:
I

[ 危险类别 ]:
4.3

详细合成路线

三氯氢硅上游产品

三氯氢硅下游产品

1.沸腾氯化法 硅粉经干燥后加入氯化沸腾炉，与通人炉中的干燥氯化氢气体在340℃进行反应。生成的粗三氯氢硅经湿法除尘器、列管冷凝器去蒸馏塔分离四氯化硅，由蒸馏塔出来的三氯氢硅气体经冷凝，制得三氯氢硅成品。其反应方程式如下：

图XIV-13 三氯硅烷的制备装置

2.使用如图所示的装置，将硅(97%)填充到石英反应管中，边通入干燥氯化氢，边反应。接受器用冷冻剂冷却。往氯化钠中加入浓硫酸产生氯化氢。反应前，将炉加热，通入干燥氢气使系统干燥，接着加热到300℃，送入氯化氢使其反应。蒸馏反应产物，首先蒸出的是溶解的氯化氢，接着蒸出产物。残余组分为四氯化硅。如有必要，可再次蒸馏进行提纯。

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公司名：上海化源生化科技有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：三氯硅烷

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥108.0/25g ￥1258.0/500g ￥418.0/100g

联系人：刘佳

产品详情：三氯硅烷

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥169.9/5g

联系人：阿拉丁

产品详情：三氯硅烷

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