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四氯化锆

四氯化锆用途

【用途一】
用于制金属锆、颜料、纺织品防水剂、皮革鞣剂等
【用途二】
用于制取金属锆、颜料、纺织品防水剂、皮革鞣剂等
【用途三】
用于制金属锆、颜料、纺织品防水剂、皮革鞣剂和分析试剂等。

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四氯化锆名称

[ CAS 号 ]:
10026-11-6

[ 中文名 ]:
氯化锆(IV)

[ 英文名 ]:
Zirconium(2+) chloride (1:2)

[中文别名 ]:

四氯化锆

[英文别名 ]:

MFCD00011306
Zirconium(IV) chloride
Zirconium(2+) chloride (1:2)
Zirconium tetrachloride
EINECS 233-058-2

四氯化锆物理化学性质

[ 密度 ]:
2.8

[ 沸点 ]:
331°C

[ 熔点 ]:
437ºC

[ 分子式 ]:
Cl₄Zr

[ 分子量 ]:
233.04

[ 精确质量 ]:
319.684814

[ LogP ]:
2.75800

[ 外观性状 ]:
白色细粉末

[ 蒸汽压 ]:
1 mm Hg ( 190 °C)

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、氰化物、H发孔剂、碱类分开存放

四氯化锆MSDS

四氯化锆毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: ZH7175000

CAS REGISTRY NUMBER :: 10026-11-6

LAST UPDATED :: 199712

DATA ITEMS CITED :: 24

MOLECULAR FORMULA :: Cl4-Zr

MOLECULAR WEIGHT :: 233.02

WISWESSER LINE NOTATION :: ZR G4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1688 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 31(7-9),328,1966

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 489 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold Gastrointestinal - ulceration or bleeding from stomach Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: JNPHAG Journal de Pharmacologie. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1970- Volume(issue)/page/year: 14,437,1983 *** REVIEWS *** ACGIH TLV-TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,285,1971 OSHA PEL (Gen Indu):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(Zr)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-GERMANY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-HUNGARY:STEL 5 mg(Zr)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(Zr)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 5 mg(Zr)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-TURKEY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

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四氯化锆安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H290-H314

[ 补充危害声明 ]:
Corrosive to the respiratory tract., Reacts violently with water.

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R14;R22;R34

[ 安全声明 (欧洲) ]:
S8-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2503

[ WGK德国 ]:
3

[ RTECS号 ]:
ZH7175000

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2827399000

四氯化锆合成路线

四氯化锆上下游产品

四氯化锆上游产品

四氯化锆下游产品

四氯化锆制备

按计量摩尔比称取二氧化锆和煅烧过的炭黑，混合均匀后放入瓷舟。将瓷舟置于瓷管中，在氯气流中加热到500℃进行煅烧。用捕集器在室温下收集产物。考虑到四氯化锆在331℃升华，可用600mm长的管子，在300～350℃于氢气流中将其重新升华，以除去氯化锆中氧化物及三氯化铁。

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四氯化锆海关

[ 海关编码 ]: 2827399000

四氯化锆文献

Design of Zeolitic Imidazolate Framework Derived Nitrogen-Doped Nanoporous Carbons Containing Metal Species for Carbon Dioxide Fixation Reactions.

ChemSusChem 8 , 3905-12, (2015)

Various N-doped nanoporous carbons containing metal species were prepared by direct thermal conversion of zeolitic imidazolate frameworks (ZIFs; ZIF-7, -8, -9, and -67) at different temperatures (600,...

Zirconium ions up-regulate the BMP/SMAD signaling pathway and promote the proliferation and differentiation of human osteoblasts.

PLoS ONE 10(1) , e0113426, (2015)

Zirconium (Zr) is an element commonly used in dental and orthopedic implants either as zirconia (ZrO2) or in metal alloys. It can also be incorporated into calcium silicate-based ceramics. However, th...

Ordered, mesoporous metal phosphonate materials with microporous crystalline walls for selective separation techniques.

Small 7(13) , 1827-37, (2011)

Ordered, hexagonal, mesoporous metal (Ti, Zr, V, Al)-phosphonate materials with microporous crystalline walls are synthesized through a microwave-assisted procedure by using triblock copolymer F127 as...

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四氯化锆

四氯化锆用途

四氯化锆名称

四氯化锆物理化学性质

四氯化锆MSDS

详细MSDS(安全技术说明书)

四氯化锆毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

四氯化锆安全信息

四氯化锆合成路线

详细合成路线

四氯化锆上下游产品

四氯化锆上游产品

四氯化锆下游产品

四氯化锆制备

四氯化锆海关

四氯化锆文献

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