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氯化锗

氯化锗用途

【用途一】
制备半导体锗的原料。光导纤维掺杂剂。
【用途二】
主要用于制作光导纤维及高纯二氧化锗等的原料。也用于微波制备Ge2Cl6, 一种无色结晶物质,用于更深地研究低价锗化合物。
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氯化锗名称

[ CAS 号 ]:
10038-98-9

[ 中文名 ]:
四氯化锗

[ 英文名 ]:
Germanium chloride

[中文别名 ]:

[英文别名 ]:

氯化锗物理化学性质

[ 密度 ]:
1.844

[ 沸点 ]:
82-84ºC

[ 熔点 ]:
-49.5ºC

[ 分子式 ]:
Cl4Ge

[ 分子量 ]:
214.45200

[ 闪点 ]:
83.1°C

[ 精确质量 ]:
213.79700

[ LogP ]:
2.37720

[ 外观性状 ]:
无色,冒烟的液体

[ 蒸汽压 ]:
76 mm Hg ( 20 °C)

[ 折射率 ]:
1.4644

[ 储存条件 ]:
库房通风低温干燥,与碱类、食品添加剂分开存放

[ 水溶解性 ]:
DECOMPOSES

氯化锗MSDS

氯化锗毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LY5225000
CHEMICAL NAME :
Germanium chloride
CAS REGISTRY NUMBER :
10038-98-9
LAST UPDATED :
199701
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
Cl4-Ge
MOLECULAR WEIGHT :
214.39
WISWESSER LINE NOTATION :
.GE..G4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(4),57,1964 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
44 gm/m3/2H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - conjunctive irritation Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 12(5),51,1968
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02625 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/m3/2H/40D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Blood - hemorrhage Related to Chronic Data - death
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(4),57,1964 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5834 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 1717 (estimated) No. of Female Employees: 195 (estimated)
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氯化锗安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H330

[ 补充危害声明 ]:
Reacts violently with water.

[ 警示性声明 ]:
P260-P280-P284-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R14;R34

[ 安全声明 (欧洲) ]:
S25-S36/37/39-S45-S8

[ 危险品运输编码 ]:
UN 3390

[ WGK德国 ]:
3

[ RTECS号 ]:
LY5225000

[ 包装等级 ]:
II

氯化锗合成路线

氯化锗上下游产品

氯化锗制备

氧化锗盐酸法 将二氧化锗加入带有回流冷凝器的反应器中,边加热边滴加盐酸进行反应,生成四氯化锗液体。通过精馏、冷凝,制得四氯化锗成品。其反应式如下: 合成法 图XIV-17 四氯化锗的制备装置 将金属锗加入反应器中并通入氯气于250℃进行氯化反应,生成四氯化锗,冷却至-20℃,经精馏、冷凝,制得四氯化锗成品。其反应式如下:
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氯化锗文献

Electrochemical vapor deposition of semiconductors from gas phase with a solid membrane cell.

J. Am. Chem. Soc. 137 , 6638-42, (2015)

We demonstrate the feasibility of semiconductor deposition via the electrochemical reduction of gaseous precursors by the use of an anhydrous proton-conducting membrane, the solid acid CsHSO4, at 165 ...

The Crystal Structure and Raman Spectrum of Ge(5)Cl(12).GeCl(4) and the Vibrational Spectrum of Ge(2)Cl(6).

Inorg. Chem. 37 , 6032, (1998)

The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is ver...

Catalytic conversion of carbohydrates into 5-hydroxymethylfurfural by germanium(IV) chloride in ionic liquids.

ChemSusChem 4(1) , 131-8, (2011)

Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly ...


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公司名:上海化源世纪贸易有限公司

区域:上海市普陀区

价格:

联系人:徐经理

产品详情:氯化锗


公司名:上海阿拉丁生化科技股份有限公司

区域:上海市浦东新区

价格:
¥10800.0/100g ¥需询单/1g ¥需询单/1g ¥需询单/1g

联系人:阿拉丁

产品详情:氯化锗


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标题:氯化锗_MSDS_用途_密度_氯化锗CAS号【10038-98-9】_化源网 地址:https://m.chemsrc.com/mip/cas/10038-98-9_343041.html