苯乙酸乙酯

苯乙酸乙酯用途

Ethyl phenylacetate 是一种天然香料,其感官阈值接近 73 µg/L。Ethyl phenylacetate 是一种毒性较小且对环境更友好的溶剂,是非诱变性的,并且是一种犹太食品添加剂。Ethyl phenylacetate 可使葡萄酒具有强烈的蜂蜜样特性。

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苯乙酸乙酯名称

[ CAS 号 ]:
101-97-3

[ 中文名 ]:
苯乙酸乙酯

[ 英文名 ]:
Ethyl phenylacetate

[中文别名 ]:

甲苯甲酸乙酯

[英文别名 ]:

Phenylacetic acid ethyl ester
Ethyl benzeneacetate
Ethyl 2-phenylethanoate
Ethyl 2-phenylacetate
MFCD00009178
2-Phenylacetic acid ethyl ester
Ethyl phenylacetate
Benzeneacetic acid, ethyl ester
EINECS 202-993-8
2OV1R

苯乙酸乙酯生物活性

[ 描述 ]:

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Tat L, et al. Sweet-like off-flavor in Aglianico del Vulture wine: ethyl phenylacetate as the mainly involved compound. J Agric Food Chem. 2007 Jun 27;55(13):5205-12.

[2]. Clark L, et al. Aerosolized essential oils and individual natural product compounds as brown treesnake repellents. Pest Manag Sci. 2002 Aug;58(8):775-83.

[3]. Mary M. Caruso, et al. Full Recovery of Fracture Toughness Using a Nontoxic Solvent-Based Self-Healing System. Advances in Functional Materials 18(13), 1898-1904, (2008).

苯乙酸乙酯物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
224.8±9.0 °C at 760 mmHg

[ 熔点 ]:
-29 °C

[ 分子式 ]:
C₁₀H₁₂O₂

[ 分子量 ]:
164.201

[ 闪点 ]:
77.8±0.0 °C

[ 精确质量 ]:
164.083725

[ PSA ]:
26.30000

[ LogP ]:
2.50

[ 外观性状 ]:
苯乙酸乙酯(101-97-3)为无色液体。熔点-29℃,沸点226℃，135℃（4.27kPa），121℃（2.67kPa），相对密度1.0333（20/4℃），折光率1.4975，闪点77℃。能与乙醇、乙醚、苯和氯仿混溶，不溶于水。有令人愉快的气味。

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.502

[ 储存条件 ]:
室温

[ 水溶解性 ]:
insoluble

苯乙酸乙酯MSDS

详细MSDS(安全技术说明书)

苯乙酸乙酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AJ2824000

CHEMICAL NAME :: Acetic acid, phenyl-, ethyl ester

CAS REGISTRY NUMBER :: 101-97-3

BEILSTEIN REFERENCE NO. :: 0509140

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C10-H12-O2

MOLECULAR WEIGHT :: 164.22

WISWESSER LINE NOTATION :: 2OV1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: DNA repair

TEST SYSTEM :: Bacteria - Bacillus subtilis

DOSE/DURATION :: 21 mg/disc

REFERENCE :: OIGZDE Osaka-shi Igakkai Zasshi. Journal of Osaka City Medical Association. (Osaka-shi Igakkai, c/o Osaka-shiritsu Daigaku Igakubu, 1-4-54 Asahi-cho, Abeno-ku, Osaka, 545, Japan) V.24- 1975- Volume(issue)/page/year: 34,267,1985 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4791 No. of Facilities: 12 (estimated) No. of Industries: 2 No. of Occupations: 6 No. of Employees: 1989 (estimated) No. of Female Employees: 276 (estimated)

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苯乙酸乙酯安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
F+

[ 安全声明 (欧洲) ]:
S23-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
AJ2824000

[ 海关编码 ]:
2918230000

苯乙酸乙酯上下游产品

苯乙酸乙酯上游产品

苯乙酸乙酯下游产品

苯乙酸乙酯制备

1. 由苯乙腈、乙醇和硫酸回流反应而得。也可由苯乙酸与乙醇在硫酸作用下酯化制得苯乙酸乙酯，收率90%。另一种生产方法是由苯乙酰胺经水解、酯化而得。还有苯乙酸法：由苯乙酸与乙醇经酯化而得。

2. 烟草：FC，18。

3.制法：

于装有搅拌器、回流冷凝器的反应瓶中，加入95%的乙醇155mL，冰水浴冷却下慢慢加入浓硫酸150g，再加入苄基腈（2）75g（0.64mol），搅拌下加热回流8h。冷后倒入400g冰水中，分出有机层，加入乙醚75mL，用饱和碳酸氢钠溶液洗涤，水洗，无水硫酸钙干燥。蒸出乙醚。剩余物继续蒸馏，收集225～229℃的馏分，得苯乙酸乙酯（1）约90g，收率86%。

^4.制法：

于装有搅拌器、温度计、滴液漏斗的反应瓶中，加入0.2mol的二苯基镉，干燥的THF60mL，冰浴冷却，搅拌下慢慢滴加溴乙酸乙酯（2）16.7g（0.1mol）溶于15mLTHF的溶液。加完后冰浴中继续搅拌反应10h。加入过量的饱和氯化铵水溶液进行水解。水蒸气蒸馏。开始收集150mL，其中主要为THF，浓缩后几乎没有剩余物。再收集400mL作为第二馏分。后馏分中不含羰基化合物，但含有联苯。第二馏分用乙醚提取，减压蒸馏，收集66～71℃/80～133Pa的馏分，得化合物（1）8.6g，收率53%。

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苯乙酸乙酯海关

[ 海关编码 ]: 2916399090

[ 中文概述 ]:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

苯乙酸乙酯文献

Volatile Compounds from Grape Skin, Juice and Wine from Five Interspecific Hybrid Grape Cultivars Grown in Québec (Canada) for Wine Production.

Molecules 20 , 10980-1016, (2015)

Developed from crosses between Vitis vinifera and North American Vitis species, interspecific hybrid grape varieties are becoming economically significant in northern areas, where they are now extensi...

Mosquito odorant receptor for DEET and methyl jasmonate.

Proc. Natl. Acad. Sci. U. S. A. 111(46) , 16592-7, (2014)

Insect repellents are important prophylactic tools for travelers and populations living in endemic areas of malaria, dengue, encephalitis, and other vector-borne diseases. DEET (N,N-diethyl-3-methylbe...

Influence of Grape Composition on Red Wine Ester Profile: Comparison between Cabernet Sauvignon and Shiraz Cultivars from Australian Warm Climate.

J. Agric. Food Chem. 63 , 4664-72, (2015)

The relationship between grape composition and subsequent red wine ester profile was examined. Cabernet Sauvignon and Shiraz, from the same Australian very warm climate vineyard, were harvested at two...

更多文献

苯乙酸乙酯

苯乙酸乙酯用途

苯乙酸乙酯名称

苯乙酸乙酯生物活性

苯乙酸乙酯物理化学性质

苯乙酸乙酯MSDS

详细MSDS(安全技术说明书)

苯乙酸乙酯毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

苯乙酸乙酯安全信息

苯乙酸乙酯上下游产品

苯乙酸乙酯上游产品

苯乙酸乙酯下游产品

苯乙酸乙酯制备

苯乙酸乙酯海关

苯乙酸乙酯文献

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