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叔丁基二甲基硅氧烷基乙醛

叔丁基二甲基硅氧烷基乙醛名称

[ CAS 号 ]:
102191-92-4

[ 中文名 ]:
叔丁基二甲基硅氧烷基乙醛

[ 英文名 ]:
{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde

[中文别名 ]:

(叔丁基二甲基硅杂氧基)乙醛

[英文别名 ]:

MFCD01321229
2-[tert-butyl(dimethyl)silyl]oxyacetaldehyde
(tert-Butyldimethylsiloxy)acetaldehyde

叔丁基二甲基硅氧烷基乙醛物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
161.0±23.0 °C at 760 mmHg

[ 熔点 ]:
165-167ºC

[ 分子式 ]:
C₈H₁₈O₂Si

[ 分子量 ]:
174.313

[ 闪点 ]:
42.7±18.2 °C

[ 精确质量 ]:
174.107605

[ PSA ]:
26.30000

[ LogP ]:
2.61

[ 外观性状 ]:
透明无色至稻黄色的液体

[ 蒸汽压 ]:
2.3±0.3 mmHg at 25°C

[ 折射率 ]:
1.412

[ 储存条件 ]:
below 5° C

叔丁基二甲基硅氧烷基乙醛MSDS

叔丁基二甲基硅氧烷基乙醛安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
UN 1989

[ WGK德国 ]:
3

[ 海关编码 ]:
2931900090

叔丁基二甲基硅氧烷基乙醛合成路线

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叔丁基二甲基硅氧烷基乙醛海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

叔丁基二甲基硅氧烷基乙醛文献

Enantioselective total synthesis of (-)-dactylolide.

Org. Lett. 8(6) , 1117-1120, (2006)

[reaction: see text] The enantioselective total synthesis of (-)-dactylolide is reported. The absolute stereochemistry of the tetrahydropyran was established by catalytic asymmetric Jacobsen hetero-Di...

One-pot enantioselective syntheses of iminosugar derivatives using organocatalytic anti-michael-anti-aza-Henry reactions.

Org. Lett. 12(22) , 5250-3, (2010)

Organocatalyst-controlled asymmetric anti-Michael reactions of (tert-butyldimethylsilyloxy)acetaldehyde with a range of nitroolefins, followed by an intermolecular aza-Henry reaction with imine, provi...

Organocatalytic asymmetric assembly reactions for the syntheses of carbohydrate derivatives by intermolecular Michael-Henry reactions.

Proc. Natl. Acad. Sci. U. S. A. 107(48) , 20672-7, (2010)

Given the significance of carbohydrates in life, medicine, and industry, the development of simple and efficient de novo methods to synthesize carbohydrates are highly desirable. Organocatalytic asymm...

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