对苯二异氰酸酯
对苯二异氰酸酯名称
[ CAS 号 ]:
104-49-4
[ 中文名 ]:
对苯二异氰酸酯
[ 英文名 ]:
1,4-Diisocyanatobenzene
[中文别名 ]:
[英文别名 ]:
- 1,4-Phenylene Diisocyanate
- Benzene, 1,4-diisocyanato-
- Benzene 1,4-Diisocyanate
- EINECS 203-207-6
- MFCD00002025
- 1,4-Diisocyanatobenzene
对苯二异氰酸酯物理化学性质
[ 密度 ]:
1.2±0.1 g/cm3
[ 沸点 ]:
236.2±23.0 °C at 760 mmHg
[ 熔点 ]:
96-99 °C(lit.)
[ 分子式 ]:
C8H4N2O2
[ 分子量 ]:
160.130
[ 闪点 ]:
92.4±28.0 °C
[ 精确质量 ]:
160.027283
[ PSA ]:
58.86000
[ LogP ]:
2.85
[ 外观性状 ]:
白色至淡黄色晶体
[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C
[ 折射率 ]:
1.567
[ 储存条件 ]:
0-10°C;存放于惰性气体之中;避免湿气 (分解),加热
[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidising agents, strong alkalies, strong acids, alcohols, amines. Moisture sensitive.
对苯二异氰酸酯MSDS
对苯二异氰酸酯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CZ6150000
- CHEMICAL NAME :
- Benzene, 1,4-diisocyanato-
- CAS REGISTRY NUMBER :
- 104-49-4
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 10
- MOLECULAR FORMULA :
- C8-H4-N2-O2
- MOLECULAR WEIGHT :
- 160.14
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530176 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 335 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0543429 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 77100 ug/kg/7H/5D-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Related to Chronic Data - death
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530223
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 77100 ug/kg/7H/5D-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Related to Chronic Data - death
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530223
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Mammal - cat
- DOSE/DURATION :
- 77100 ug/kg/7H/5D-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - changes in structure or function of salivary glands
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530223
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 77100 ug/kg/7H/5D-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Related to Chronic Data - death
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530223
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 77100 ug/kg/7H/5D-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Related to Chronic Data - death
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530223
对苯二异氰酸酯安全信息
[ 符号 ]:
GHS05, GHS07, GHS08
[ 信号词 ]:
Danger
[ 危害声明 ]:
H302 + H312 + H332-H315-H318-H334
[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P342 + P311
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful
[ 风险声明 (欧洲) ]:
R20/21/22;R36/37/38;R42
[ 安全声明 (欧洲) ]:
S22-S26-S36/37
[ 危险品运输编码 ]:
UN 2811 6.1/PG 3
[ WGK德国 ]:
3
[ RTECS号 ]:
CZ6150000
[ 危险类别 ]:
6.1
[ 海关编码 ]:
2929109000
对苯二异氰酸酯合成路线
对苯二异氰酸酯上下游产品
对苯二异氰酸酯上游产品
对苯二异氰酸酯下游产品
对苯二异氰酸酯海关
[ 海关编码 ]: 2929109000
[ 中文概述 ]:
2929109000. 其他异氰酸酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2929109000. other isocyanates. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
对苯二异氰酸酯文献
Beilstein J. Org. Chem. 11 , 2355-64, (2016)
Emulsions stabilized by colloidal particles are known as Pickering emulsions. To date, soft microgel particles as well as inorganic and organic particles have been utilized as Pickering emulsifiers. A...
Enzyme immobilization on silane-modified surface through short linkers: fate of interfacial phases and impact on catalytic activity.Langmuir 30(14) , 4066-77, (2014)
We investigated the mechanism of enzyme immobilization on silanized surfaces through coupling agents (cross-linkers) in order to understand the role of these molecules on interfacial processes and the...
Molecular layer deposition of functional thin films for advanced lithographic patterning.ACS Appl. Mater. Interfaces 3(2) , 505-11, (2011)
Photoresist materials comprise one of the main challenges faced by lithography to meet the requirements of electronic device size scaling. Here we report for the first time the use of molecular layer ...
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