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三(三甲基硅基)磷酸酯

三(三甲基硅基)磷酸酯名称

[ CAS 号 ]:
10497-05-9

[ 中文名 ]:
磷酸三(三甲基硅基)酯

[ 英文名 ]:
Tris(Trimethylsilyl) Phosphate

[中文别名 ]:

三(三甲基硅基)磷酸酯

[英文别名 ]:

Phosphoric Acid Tris(trimethylsilyl) Ester
EINECS 234-028-1
Tris(trimethylsilyl) Phosphate
MFCD00008267

三(三甲基硅基)磷酸酯物理化学性质

[ 密度 ]:
0.945 g/mL at 25 °C(lit.)

[ 沸点 ]:
228-229 °C720 mm Hg(lit.)

[ 熔点 ]:
3-4 °C(lit.)

[ 分子式 ]:
C₉H₂₇O₄PSi₃

[ 分子量 ]:
314.53900

[ 闪点 ]:
76 °F

[ 精确质量 ]:
314.09500

[ PSA ]:
54.57000

[ LogP ]:
4.64900

[ 外观性状 ]:
液体;Colorless to Light yellow to Light orange clear liquid

[ 蒸汽压 ]:
0.0977mmHg at 25°C

[ 折射率 ]:
n20/D 1.409(lit.)

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)

三(三甲基硅基)磷酸酯MSDS

三(三甲基硅基)磷酸酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TC9700000

CHEMICAL NAME :: Phosphoric acid, tris(trimethylsilyl) ester

CAS REGISTRY NUMBER :: 10497-05-9

BEILSTEIN REFERENCE NO. :: 1794624

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C9-H27-O4-P-Si3

MOLECULAR WEIGHT :: 314.60

WISWESSER LINE NOTATION :: 1-SI-1&1&-OPO&O-SI-1&1&1&O-SI-1&1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3440 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1233,1986

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三(三甲基硅基)磷酸酯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H315-H319-H335

[ 警示性声明 ]:
P210-P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F: Flammable;Xi: Irritant;

[ 风险声明 (欧洲) ]:
R11

[ 安全声明 (欧洲) ]:
S16-S26-S36

[ 危险品运输编码 ]:
UN 1993 3/PG 2

[ WGK德国 ]:
2

[ RTECS号 ]:
TC9700000

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

[ 海关编码 ]:
2931900090

三(三甲基硅基)磷酸酯合成路线

三(三甲基硅基)磷酸酯上下游产品

三(三甲基硅基)磷酸酯上游产品

三(三甲基硅基)磷酸酯下游产品

三(三甲基硅基)磷酸酯海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

三(三甲基硅基)磷酸酯文献

Adamantane-like aluminum amide-phosphate from alumazene.

Inorg. Chem. 41(25) , 6914-8, (2002)

A dealkylsilylation reaction between alumazene [2,6-(i-Pr)(2)C(6)H(3)NAlMe](3) (1) and tris(trimethylsilyl) ester of phosphoric acid (2) in a 1:3 molar ratio provides the heteroadamantane molecule (Me...

The use of [18O4]phosphoric acid in the quantitation of phosphate by gas-liquid chromatography-mass spectrometry analysis.

Anal. Biochem. 107(2) , 324-31, (1980)

Tris (trimethylsilyl) phosphate: A film-forming additive for high voltage cathode material in lithium-ion batteries. Yan G, et al.

J. Power Sources 248 , 1306-11, (2014)

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