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硫化丙烯

硫化丙烯用途

有机合成

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硫化丙烯名称

[ CAS 号 ]:
1072-43-1

[ 中文名 ]:
硫化丙烯

[ 英文名 ]:
2-Methylthiirane

[中文别名 ]:

[英文别名 ]:

Thiirane, 2-methyl-
Methylethylene Sulfide
MFCD00005160
2-Methylthiirane
EINECS 214-007-3
Propylene sulfide

硫化丙烯物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
75.9±8.0 °C at 760 mmHg

[ 分子式 ]:
C₃H₆S

[ 分子量 ]:
74.145

[ 闪点 ]:
10.0±0.0 °C

[ 精确质量 ]:
74.019020

[ PSA ]:
25.30000

[ LogP ]:
0.70

[ 外观性状 ]:
液体;Colorless to Almost colorless clear liquid

[ 蒸汽压 ]:
113.2±0.1 mmHg at 25°C

[ 折射率 ]:
1.520

[ 储存条件 ]:
2-8°C

硫化丙烯MSDS

硫化丙烯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TZ2625000

CHEMICAL NAME :: Propane, 1,2-epithio-

CAS REGISTRY NUMBER :: 1072-43-1

BEILSTEIN REFERENCE NO. :: 0383559

LAST UPDATED :: 199701

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C3-H6-S

MOLECULAR WEIGHT :: 74.15

WISWESSER LINE NOTATION :: T3STJ B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 254 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - respiratory depression

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 25,560,1964

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 660 ppm/6H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - fibrosis, focal (pneumoconiosis) Lungs, Thorax, or Respiration - acute pulmonary edema Blood - hemorrhage

REFERENCE :: BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 6,509,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 44 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - ataxia Lungs, Thorax, or Respiration - cyanosis

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 25,560,1964

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: RAREAE Radiation Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1954- Volume(issue)/page/year: 7,13,1957 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7180 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1822 (estimated) No. of Female Employees: 272 (estimated)

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硫化丙烯安全信息

[ 符号 ]:

GHS02, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H301-H315-H319-H332

[ 警示性声明 ]:
P210-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F: Flammable;Xn: Harmful;

[ 风险声明 (欧洲) ]:
11-20/22-36/38

[ 安全声明 (欧洲) ]:
S16-S26-S36

[ 危险品运输编码 ]:
UN 1992 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
TZ2625000

[ 包装等级 ]:
II

[ 危险类别 ]:
3.1

硫化丙烯合成路线

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