反-1,4-二氯-2-丁烯
反-1,4-二氯-2-丁烯用途
反式-1,4-二氯-2-丁烯(110-57-6)用于合成吡咯芬。同时也用于己二腈、丁二醇、六亚甲基二胺、氯丁二烯、四氢呋喃的生产。
反-1,4-二氯-2-丁烯名称
[ CAS 号 ]:
110-57-6
[ 中文名 ]:
反式1.4-二氯-2-丁烯
[ 英文名 ]:
trans-1,4-Dichlorobutene
[中文别名 ]:
[英文别名 ]:
- 2-Butene, 1,4-dichloro-, (E)-
- Toluene,2,5-dichloro
- trans-1,4-Dichlorobutene
- (2E)-1,4-Dichloro-2-butene
- 1,4-Dichloro-2-butene
- Benzene,1,4-dichloro-2-methyl
- trans 1,4-Dichloro-2-butene
- (E)-1,4-Dichloro-2-butene
- EINECS 203-779-7
- TRANS-1,4-DICHLORO-2-BUTYLENE
反-1,4-二氯-2-丁烯物理化学性质
[ 密度 ]:
1.1±0.1 g/cm3
[ 沸点 ]:
155.5±0.0 °C at 760 mmHg
[ 熔点 ]:
1-3ºC(lit.)
[ 分子式 ]:
C4H6Cl2
[ 分子量 ]:
124.996
[ 闪点 ]:
54.4±0.0 °C
[ 精确质量 ]:
123.984657
[ LogP ]:
1.97
[ 外观性状 ]:
无色液体带有一种独特的气味
[ 蒸汽压 ]:
3.9±0.2 mmHg at 25°C
[ 折射率 ]:
1.459
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开存放
[ 水溶解性 ]:
水溶性:不溶;水溶解度:850 mg/l 25 °C;可溶于:苯,乙醚,氯仿,丙酮,醇
反-1,4-二氯-2-丁烯MSDS
反-1,4-二氯-2-丁烯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- EM4903000
- CHEMICAL NAME :
- 2-Butene, 1,4-dichloro-, (E)-
- CAS REGISTRY NUMBER :
- 110-57-6
- BEILSTEIN REFERENCE NO. :
- 1719693
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 9
- MOLECULAR FORMULA :
- C4-H6-Cl2
- MOLECULAR WEIGHT :
- 125.00
- WISWESSER LINE NOTATION :
- G2U2G -T
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 86 ppm/4H
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - other changes Gastrointestinal - changes in structure or function of salivary glands
- REFERENCE :
- AIHAM* Annual Meeting of American Industrial Hygiene Association. (Akron, OH) For publisher information, see AIHAAP. Volume(issue)/page/year: -,-,1968 ** TUMORIGENIC DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 150 mg/kg/77W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
- REFERENCE :
- CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 35,2553,1975
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 150 mg/kg/77W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Tumorigenic - tumors at site of application
- REFERENCE :
- CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 35,2553,1975 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 15,149,1977 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 15,149,1977 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987
反-1,4-二氯-2-丁烯安全信息
[ 符号 ]:
GHS02, GHS05, GHS06
[ 信号词 ]:
Danger
[ 危害声明 ]:
H226-H301-H312-H314-H330
[ 警示性声明 ]:
P260-P280-P284-P305 + P351 + P338-P310
[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
T+,T,F,N
[ 风险声明 (欧洲) ]:
R10
[ 安全声明 (欧洲) ]:
53-23-26-36/37/39-45-36/37-99-61-60
[ 危险品运输编码 ]:
UN 3390 6.1/PG 1
[ WGK德国 ]:
3
[ RTECS号 ]:
EM4903000
[ 包装等级 ]:
II
[ 危险类别 ]:
6.1(a)
[ 海关编码 ]:
2903299090
反-1,4-二氯-2-丁烯合成路线
反-1,4-二氯-2-丁烯上下游产品
反-1,4-二氯-2-丁烯上游产品
反-1,4-二氯-2-丁烯下游产品
反-1,4-二氯-2-丁烯海关
[ 海关编码 ]: 2903299090
[ 中文概述 ]:
HS: 2903299090. 其他无环烃的不饱和氯化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
反-1,4-二氯-2-丁烯文献
Bioorg. Med. Chem. 16 , 5720-32, (2008)
The risk of the presence of haloacetic acids in drinking water as chlorination by-products and the shortage of experimental mutagenicity data for most of them requires a research work. This paper desc...
Synthesis and biological properties of 9-(trans-4-hydroxy-2-buten-1-yl)adenine and guanine: open-chain analogues of neplanocin A.J. Med. Chem. 30(2) , 437-40, (1987)
Alkylation of adenine (5a) or 2-amino-6-chloropurine (5b) with excess trans-1,4-dichloro-2-butene (4), effected by K2CO3 in dimethyl sulfoxide or tetra-n-butylammonium fluoride in tetrahydrofuran, led...
Effect of isomers of swainsonine on glycosidase activity and glycoprotein processing.Biochemistry 26(9) , 2502-10, (1987)
The chemical synthesis of swainsonine [(1S,2R,8R,8 alpha R)-trihydroxyindolizidine] from trans-1,4-dichloro-2-butene was previously described [Adams, C. E., Walker, F. J., & Sharpless, K. B. (1985) J....
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产品详情:[Perfemiker]反-1,4-二氯-2-丁烯,95%
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