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N-甲基丁胺

N-甲基丁胺用途

用于有机合成。

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N-甲基丁胺名称

[ CAS 号 ]:
110-68-9

[ 中文名 ]:
甲基丁胺

[ 英文名 ]:
N-Methylbutylamine

[中文别名 ]:

[英文别名 ]:

N-methyl-N-n-butylamine
N-Methylbutylamine
N-butyl-methylamine
n-methyl-butylamin
Methylaminobutane
UNII-61NTK0473L
N-methylbutanamine
n-methylbutan-1-amine
Methylbutylamine
N-Butylmethylamine

N-甲基丁胺物理化学性质

[ 密度 ]:
0.7±0.1 g/cm3

[ 沸点 ]:
91.5±3.0 °C at 760 mmHg

[ 熔点 ]:
-75 °C

[ 分子式 ]:
C₅H₁₃N

[ 分子量 ]:
87.163

[ 闪点 ]:
1.7±0.0 °C

[ 精确质量 ]:
87.104797

[ PSA ]:
12.03000

[ LogP ]:
1.16

[ 蒸汽压 ]:
53.7±0.2 mmHg at 25°C

[ 折射率 ]:
1.396

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

N-甲基丁胺MSDS

N-甲基丁胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EO5250000

CHEMICAL NAME :: Butylamine, N-methyl-

CAS REGISTRY NUMBER :: 110-68-9

LAST UPDATED :: 199709

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C5-H13-N

MOLECULAR WEIGHT :: 87.19

WISWESSER LINE NOTATION :: 4M1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 7/6/1970 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 420 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 7/6/1970

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2000 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 7/6/1970

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 471 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 88,82,1946

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 122 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 88,82,1946

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1260 uL/kg

TOXIC EFFECTS :: Skin and Appendages - primary irritation (after topical exposure)

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4318 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 851 (estimated) No. of Female Employees: 187 (estimated)

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N-甲基丁胺安全信息

[ 符号 ]:

GHS02, GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302 + H332-H311-H314

[ 警示性声明 ]:
P210-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Highlyflammable;C:Corrosive;

[ 风险声明 (欧洲) ]:
R11;R21/22;R34

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2945 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
EO5250000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
2921199090

N-甲基丁胺合成路线

N-甲基丁胺上下游产品

N-甲基丁胺上游产品

N-甲基丁胺下游产品

N-甲基丁胺海关

[ 海关编码 ]: 2921199090

[ 中文概述 ]:
2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

N-甲基丁胺文献

Synthesis and evaluation of estradiol derivatives with 16 alpha-(bromoalkylamide), 16 alpha-(bromoalkyl) or 16 alpha-(bromoalkynyl) side chain as inhibitors of 17 beta-hydroxysteroid dehydrogenase type 1 without estrogenic activity.

Bioorg. Med. Chem. 4(10) , 1617-28, (1996)

To develop inhibitors of 17 beta-hydroxysteroid dehydrogenase (17 beta-HSD) without residual estrogenic activity, the synthesis of 16 alpha-(bromoalkylamide) derivatives of estradiol was performed sta...

A Base-Catalyzed Domino-Isomerization-Hydroamination Reaction-A New Synthetic Route to Amphetamines. Hartung CG, et al.

Tetrahedron 56(29) , 5157-62, (2000)

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