2-癸醇

2-癸醇用途

Decan-2-ol is used to study the substrate spectrum of phytanoyl-CoA hydroxylase with regard to the length of both the acyl chain and the branch at position. It is used to develop a miniature catalytic reactor for the oxidation of alcohols with O2 in supercritical CO2.

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2-癸醇名称

[ CAS 号 ]:
1120-06-5

[ 中文名 ]:
2-癸醇

[ 英文名 ]:
2-decanol

[中文别名 ]:

仲癸醇

[英文别名 ]:

MFCD00004594
EINECS 214-296-6
2-Hydroxydecane
sec-Decanol
Methyl octyl carbinol
2-DECANOL
rac-2-decanol
2-Decyl Alcohol
Methyl-n-octylcarbinol
decane-2-ol

2-癸醇物理化学性质

[ 密度 ]:
0.827 g/mL at 25 °C(lit.)

[ 沸点 ]:
211 °C(lit.)

[ 熔点 ]:
−6-−4 °C(lit.)

[ 分子式 ]:
C₁₀H₂₂O

[ 分子量 ]:
158.28100

[ 闪点 ]:
185 °F

[ 精确质量 ]:
158.16700

[ PSA ]:
20.23000

[ LogP ]:
3.11780

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
0.0393mmHg at 25°C

[ 折射率 ]:
n20/D 1.434(lit.)

[ 储存条件 ]:
室温

2-癸醇MSDS

详细MSDS(安全技术说明书)

2-癸醇安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H319

[ 警示性声明 ]:
P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R36

[ 安全声明 (欧洲) ]:
S26-S61

[ 危险品运输编码 ]:
UN 3082 9/PG 3

[ WGK德国 ]:
3

2-癸醇合成路线

详细合成路线

2-癸醇上下游产品

2-癸醇上游产品

2-癸醇下游产品

2-癸醇制备

1.制法：

于装有搅拌器、温度计的反应瓶中，加入1,2-环氧癸烷(2)0.46g（3mmol），无水乙醇1mL，干燥的10%的Pd-C催化剂0.12g，而后加入甲酸铵0.414g(9mmol),于23℃搅拌反应约48h，直至TLC检测表明反应完全。过滤，滤液浓缩后过硅胶柱纯化，乙酸乙酯-己烷洗脱，得化合物(1) ^①,收率81%。注：①采用类似方法可以合成如下各种醇类化合物(表I-5-1)。

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2-癸醇文献

Further studies on the substrate spectrum of phytanoyl-CoA hydroxylase: implications for Refsum disease?

J. Lipid Res. 44(12) , 2349-55, (2003)

Refsum disease is a peroxisomal disorder characterized by adult-onset retinitis pigmentosa, anosmia, sensory neuropathy, ataxia, and an accumulation of phytanic acid in plasma and tissues. Approximate...

Highly sustainable catalytic dehydrogenation of alcohols with evolution of hydrogen gas. Ligthart GBWL, et al.

Tetrahedron Lett. 44(7) , 1507-1509, (2003)

Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO₂. Chapman AO, et al.

Green Chem. 12(2) , 310-315, (2010)

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