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MM 47755

MM 47755用途

MM 47755 is a new benz[a]anthracene antibiotic from a streptomycete.

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MM 47755名称

[ CAS 号 ]:
117620-87-8

[ 英文名 ]:
MM 47755

[英文别名 ]:

6-Deoxy-8-O-methylrabelomycin

MM 47755物理化学性质

[ 密度 ]:
1.39g/cm3

[ 沸点 ]:
583.3ºC at 760mmHg

[ 分子式 ]:
C₂₀H₁₆O₅

[ 分子量 ]:
336.33800

[ 闪点 ]:
214.3ºC

[ 精确质量 ]:
336.10000

[ PSA ]:
80.67000

[ LogP ]:
2.35050

[ 蒸汽压 ]:
1.89E-14mmHg at 25°C

[ 折射率 ]:
1.652

MM 47755安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H410

[ 警示性声明 ]:
P273-P501

[ 危险品运输编码 ]:
UN 3077 9 / PGIII

MM 47755文献

Angucyclinone antibiotics: total syntheses of YM-181741, (+)-ochromycinone, (+)-rubiginone B2, (-)-tetrangomycin, and MM-47755.

J. Org. Chem. 72(16) , 6116-26, (2007)

A concise and highly enantioselective route has been developed for the synthesis of angucyclinone-type natural products. Utilizing this strategy, total syntheses of five natural products YM-181741, (+...

Total synthesis of (-)-8-O-methyltetrangomycin (MM 47755).

Org. Lett. 8(12) , 2507-10, (2006)

A stereoselective total synthesis of the natural antibiotic (-)-8-O-methyltetrangomycin 1 is reported. The essential steps for this convergent synthesis are the transformation of a geraniol epoxide in...

The cobalt way to angucyclinones: asymmetric total synthesis of the antibiotics (+)-rubiginone B2, (-)-tetrangomycin, and (-)-8-O-methyltetrangomycin.

Chemistry 16(29) , 8805-21, (2010)

A cobalt(I)-mediated convergent and asymmetric total synthesis of angucyclinones with an aromatic B ring has been developed. In the course of our research, we synthesized three naturally occurring ang...

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