[Pd(dppp)(H2O)2](BF4)2

[ 熔点 ]:
175-200°C (decomposition)

[ 分子式 ]:
C₂₇H₃₀BF₄O₂P₂Pd+

[ 分子量 ]:
641.71

[ 危险品运输编码 ]:
NONH for all modes of transport

Cationic palladium complex catalyzed diastereo- and enantioselective tandem annulation of 2-formylarylboronic acids with allenoates.

Org. Lett. 11 , 4366-4369, (2009)

Cationic palladium complex [(dppp)Pd(H(2)O)(2)](2+)(BF(4)(-))(2) catalyzed tandem annulation reactions of 2-formylarylboronic acids and allenoates produce the indenol derivatives diastereo- and enanti...

Cationic Pd(II)-catalyzed highly enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes with arylboronic acids.

Org. Lett. 7th ed., 14 , 1756-1759, (2012)

Cationic Pd(II)-catalyzed enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes was developed without the necessity of a redox system.

Control of chemoselectivity by counteranions of cationic palladium complexes: a convenient enantioselective synthesis of dihydrocoumarins.

Org. Lett. 12 , 108, (2010)

High chemoselectivity for the synthesis of two kinds of substituted coumarins controlled by the counteranions of the cationic palladium catalysts is described. The asymmetric version of the reaction f...

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