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三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物用途

用于条状﹑快状泡沫生产中的火焰阻燃剂。它是一种成本低廉的火焰阻燃剂，且具有良好的稳定性。

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三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物名称

[ CAS 号 ]:
13674-84-5

[ 中文名 ]:
三(1-氯-2-丙基)磷酸酯

[ 英文名 ]:
Tris(1-Chloro-2-Propyl) Phosphate

[中文别名 ]:

[英文别名 ]:

UNII:CRT22GFY70
tris(1-chloropropan-2-yl) phosphate
MFCD00040408
Phosphoric acid tris(2-chloro-1-methylethyl) ester
EINECS 237-158-7
Tris(1-chloro-2-propanyl) phosphate
Tris(1-Chloro-2-Propyl) Phosphate

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
358.5±22.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₁₈Cl₃O₄P

[ 分子量 ]:
327.570

[ 闪点 ]:
249.7±30.0 °C

[ 精确质量 ]:
326.000824

[ PSA ]:
54.57000

[ LogP ]:
1.53

[ 外观性状 ]:
透明无色粘性液体

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.462

[ 储存条件 ]:
室温

[ 水溶解性 ]:
<0.1 g/100 mL at 19.5 ºC

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物MSDS

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TC9000000

CHEMICAL NAME :: Phosphoric acid, tris(2-chloro-1-methylethyl) ester

CAS REGISTRY NUMBER :: 13674-84-5

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C9-H18-Cl3-O4-P

MOLECULAR WEIGHT :: 327.59

WISWESSER LINE NOTATION :: G1Y1&OPO&OY1&1GOY1&1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0517713

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 56 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#05768 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0041 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 120 (estimated) No. of Female Employees: 12 (estimated)

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三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302

[ 警示性声明 ]:
P301 + P312 + P330

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn: Harmful;

[ 风险声明 (欧洲) ]:
R22

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
1.0

[ RTECS号 ]:
TC9000000

[ 海关编码 ]:
2919900090

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物合成路线

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物上下游产品

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物上游产品

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物下游产品

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物海关

[ 海关编码 ]: 2919900090

[ 中文概述 ]:
HS:2919900090 其他磷酸酯及其盐（包括乳磷酸盐）（包括它们的卤化，磺化，硝化和亚硝化衍生物）增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2919900090 other phosphoric esters and their salts, including lactophosphates; their halogenated, sulphonated, nitrated or nitrosated derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

三(1-氯-2-丙基)磷酸酯(TCPP),异构体混合物文献

Tri (2-chloroisopropyl) phosphate--an unexpected organochlorine contaminant in some charcoal air-sampling sorbent tubes.

Am. Ind. Hyg. Assoc. J. 52(9) , 398-400; discussion 401, (1991)

Air sampling in a government building was necessary in response to reports of a cancer cluster. SKC (Eighty Four, Pa.) charcoal coconut shell-based sorbent tubes (226-01 lot 120) were recommended for ...

Chemical and microbiological parameters as possible indicators for human enteric viruses in surface water.

Int. J. Hyg. Environ. Health 213(3) , 210-6, (2010)

There are still conflicting results on the suitability of chemical and microbiological parameters as indicators for the viral contamination of surface waters. In this study, conducted over 20 months, ...

Seasonal fluctuations of organophosphate concentrations in precipitation and storm water runoff.

Chemosphere 78(8) , 958-64, (2010)

To investigate seasonal fluctuations and trends of organophosphate (flame retardants, plasticizers) concentrations in rain and snow, precipitation samples were collected in 2007-2009 period at a dense...

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