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苯胺盐酸盐

苯胺盐酸盐用途

【用途一】
用作检定糠醛和比色测定氧化物的试剂，也用于有机合成
【用途二】
糠醛的检定, 氧化剂的比色测定, 有机合成, 苯胺黑的制造,制造中间体和其它染料。

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苯胺盐酸盐名称

[ CAS 号 ]:
142-04-1

[ 中文名 ]:
盐酸苯胺

[ 英文名 ]:
Anilinium chloride

[中文别名 ]:

[英文别名 ]:

aniline,hydrochloride
Benzenamine, hydrochloride (1:1)
Aniline chlorhydrate
MFCD00012958
EINECS 205-519-8
ANILINE HYDROCHLORIDE
Aniline hydrochloride (1:1)
Aniline, hydrochloride
Anilinhydrochlorid

苯胺盐酸盐物理化学性质

[ 密度 ]:
1.2215

[ 沸点 ]:
245 °C

[ 熔点 ]:
196-198 °C(lit.)

[ 分子式 ]:
C₆H₈ClN

[ 分子量 ]:
129.587

[ 闪点 ]:
380 °F

[ 精确质量 ]:
129.034531

[ PSA ]:
26.02000

[ LogP ]:
2.65200

[ 外观性状 ]:
白色至灰白色晶体

[ 蒸汽密度 ]:
4.46 (vs air)

[ 蒸汽压 ]:
0.733mmHg at 25°C

[ 储存条件 ]:
库房通风低温干燥,与食品原料和氧化剂分开储运

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents, strong acids.

[ 水溶解性 ]:
1070 g/L (25 ºC)

苯胺盐酸盐MSDS

苯胺盐酸盐毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CY0875000

CHEMICAL NAME :: Benzenamine, hydrochloride

CAS REGISTRY NUMBER :: 142-04-1

LAST UPDATED :: 199710

DATA ITEMS CITED :: 32

MOLECULAR FORMULA :: C6-H7-N.Cl-H

MOLECULAR WEIGHT :: 129.60

WISWESSER LINE NOTATION :: ZR &GH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 840 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 460 mg/kg

TOXIC EFFECTS :: Blood - methemoglobinemia-carboxyhemoglobin

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 841 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1800 mg/kg/90D-C

TOXIC EFFECTS :: Endocrine - changes in spleen weight Blood - methemoglobinemia-carboxyhemoglobin Blood - changes in erythrocyte (RBC) count

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 910 mg/kg/7D-I

TOXIC EFFECTS :: Endocrine - changes in spleen weight Blood - changes in spleen Nutritional and Gross Metabolic - changes in iron

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 130 gm/kg/2Y-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Vascular - tumors Blood - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 238 gm/kg/2Y-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Vascular - tumors Blood - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 137 gm/kg/60W-C

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors Blood - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2163 gm/kg/2Y-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Blood - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4326 gm/kg/2Y-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Blood - tumors

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 1400 mg/kg

SEX/DURATION :: female 7-20 day(s) after conception

TOXIC EFFECTS :: Reproductive - Specific Developmental Abnormalities - blood and lymphatic systems (including spleen and marrow)

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Subcutaneous

DOSE :: 780 mg/kg

SEX/DURATION :: female 19-21 day(s) after conception

TOXIC EFFECTS :: Reproductive - Maternal Effects - other effects Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

TYPE OF TEST :: Micronucleus test

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Fibroblast

DOSE/DURATION :: 10 umol/L

REFERENCE :: JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 58,1635,1977 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,39,1982 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2301 No. of Facilities: 136 (estimated) No. of Industries: 3 No. of Occupations: 2 No. of Employees: 260 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2301 No. of Facilities: 5101 (estimated) No. of Industries: 58 No. of Occupations: 38 No. of Employees: 82371 (estimated) No. of Female Employees: 47136 (estimated)

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苯胺盐酸盐安全信息

[ 符号 ]:

GHS05, GHS06, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311 + H331-H317-H318-H341-H351-H372-H400

[ 警示性声明 ]:
Missing Phrase - N15.00950417-P260-P280-P302 + P352 + P312-P304 + P340 + P312-P305 + P351 + P338 + P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R23/24/25;R40;R41;R43;R48/23/24/25;R50;R68

[ 安全声明 (欧洲) ]:
S26-S27-S36/37/39-S45-S61-S63

[ 危险品运输编码 ]:
UN 1548 6.1/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
CY0875000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29214100

苯胺盐酸盐合成路线

苯胺盐酸盐上下游产品

苯胺盐酸盐上游产品

苯胺盐酸盐下游产品

苯胺盐酸盐海关

[ 海关编码 ]: 2921419000

[ 中文概述 ]:
HS:2921419000 苯胺盐增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921419000 aniline and its salts。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

苯胺盐酸盐文献

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Polyamide nanofiltration membranes to remove aniline in aqueous solutions.

Environ. Technol. 35(9-12) , 1175-81, (2014)

Aniline is commonly used in a number of industrial processes. It is known to be a harmful and persistent pollutant and its presence in wastewater requires treatment before disposal. In this paper, the...

Design, synthesis, and evaluation of (E)-N-substituted benzylidene–aniline derivatives as tyrosinase inhibitors

Eur. J. Med. Chem. 57 , 383-90, (2012)

We attempted to design and synthesize (E)-N-substituted benzylidene-hydroxy or methoxy-aniline derivatives and to evaluate their inhibitory effect on tyrosinase activity and anti-melanogenesis activit...

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