十六胺

【用途一】
用于纤维助剂、化肥抗结块剂、浮选剂等
【用途二】
用于制取树脂、杀虫剂和高级洗涤剂。
【用途三】
用于制取树脂；杀虫剂和高级洗涤剂。

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
321.8±5.0 °C at 760 mmHg

[ 熔点 ]:
38-47ºC

[ 分子式 ]:
C₁₆H₃₅N

[ 分子量 ]:
241.456

[ 闪点 ]:
140.6±0.0 °C

[ 精确质量 ]:
241.276947

[ PSA ]:
26.02000

[ LogP ]:
7.31

[ 外观性状 ]:
白色至灰白色固体

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.451

[ 储存条件 ]:
室温

[ 水溶解性 ]:
insoluble

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

ML9100000

CHEMICAL NAME :

1-Hexadecanamine

CAS REGISTRY NUMBER :

143-27-1

BEILSTEIN REFERENCE NO. :

1634065

LAST UPDATED :

199710

DATA ITEMS CITED :

7

MOLECULAR FORMULA :

C16-H35-N

MOLECULAR WEIGHT :

241.52

WISWESSER LINE NOTATION :

Z16

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

200 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD691-490 ** REPRODUCTIVE DATA **

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Oral

DOSE :

40 mg/kg

SEX/DURATION :

female 9 day(s) after conception

TOXIC EFFECTS :

Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - other developmental abnormalities

REFERENCE :

DZZEA7 Deutsche Zahnaerztliche Zeitschrift. (Carl Hanser Verlag, Postfach 860420, D-8000 Munich 86, Fed. Rep. Ger.) V.1- 1946- Volume(issue)/page/year: 32,861,1977

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Intraperitoneal

DOSE :

10 mg/kg

SEX/DURATION :

female 9 day(s) after conception

TOXIC EFFECTS :

Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - other developmental abnormalities

REFERENCE :

DZZEA7 Deutsche Zahnaerztliche Zeitschrift. (Carl Hanser Verlag, Postfach 860420, D-8000 Munich 86, Fed. Rep. Ger.) V.1- 1946- Volume(issue)/page/year: 32,861,1977 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83079 No. of Facilities: 13 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 125 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83079 No. of Facilities: 111 (estimated) No. of Industries: 7 No. of Occupations: 17 No. of Employees: 6933 (estimated) No. of Female Employees: 483 (estimated)

[ 符号 ]:

GHS05, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H400

[ 警示性声明 ]:
P273-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3259

[ WGK德国 ]:
2

[ RTECS号 ]:
ML9100000

[ 包装等级 ]:
III

[ 危险类别 ]:
8.0

[ 海关编码 ]:
29211980

详细合成路线

十六胺上游产品

十六胺下游产品

工业生产可由棕榈酸通氨制成十六腈，再经压力下催化加氢来制备。加氢用Co或Ni作催化剂，温度120～180℃，压力在2～10mPa。其反应式为：

由棕榈脯经还原而得。将3份棕榈脯溶于30份无水乙醇中，慢慢加入金属钠4份进行还原。反应放热，使应物呈液体状态。当加入的金属钠只能部分溶解时，可加热至60℃，并逐渐升温至120℃，始终使金属钠不全部消失。反应完全后趁热倾入水中，加入稍过量的盐酸，将生成的十六胺盐酸盐结晶滤出，用少量稀盐酸洗涤后压干。将此盐酸用20%氯氧化钠碱化，减压蒸馏，得十六胺。

[ 海关编码 ]: 2921199090

[ 中文概述 ]:
2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：十六胺

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥118.0/100g ￥348.0/500g

联系人：刘佳

产品详情：十六胺

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公司名：上海创赛科技有限公司

区域：上海市嘉定区

价格：
￥54.0/25g ￥104.0/100g ￥321.0/500g ￥1187.0/2500g

联系人：夏言

产品详情：[Perfemiker]十六胺,90%

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥102.9/100g ￥236.9/250g ￥49.9/25g ￥320.9/500g

联系人：阿拉丁

产品详情：十六胺

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公司名：中山市迪欣化工有限公司

区域：中山市三角镇

价格：
￥20.0/1000kg

联系人：陈雪萍

产品详情：十六烷基伯胺

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