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(S)-苄氧甲基环氧乙烷

(S)-苄氧甲基环氧乙烷用途

多种手性医药中间体。

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(S)-苄氧甲基环氧乙烷名称

[ CAS 号 ]:
16495-13-9

[ 中文名 ]:
(S)-苄氧甲基环氧乙烷

[ 英文名 ]:
(S)-(+)-Benzyl glycidyl ether

[中文别名 ]:

[英文别名 ]:

(2S)-2-[(Benzyloxy)methyl]oxirane
(S)-1-(Benzyloxy)-2,3-epoxypropane
Benzyl S-(+)-glycidyl ether
(S)-(+)-2-(Benzyloxymethyl)oxirane
MFCD00054428
Benzyl (S)-(+)-Glycidyl Ether
(S)-(+)-1-Benzyloxy-2,3-epoxypropane
(2S)-2-(phenylmethoxymethyl)oxirane
Oxirane, 2-[(phenylmethoxy)methyl]-, (2R)-
(S)-2-((Benzyloxy)methyl)oxirane

(S)-苄氧甲基环氧乙烷物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
252.7±15.0 °C at 760 mmHg

[ 分子式 ]:
C₁₀H₁₂O₂

[ 分子量 ]:
164.201

[ 闪点 ]:
100.9±19.9 °C

[ 精确质量 ]:
164.083725

[ PSA ]:
21.76000

[ LogP ]:
2.04

[ 外观性状 ]:
无色至淡黄色液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.535

[ 储存条件 ]:
室温

(S)-苄氧甲基环氧乙烷MSDS

详细MSDS(安全技术说明书)

(S)-苄氧甲基环氧乙烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX2860020

CHEMICAL NAME :: Propane, 1-(benzyloxy)-2,3-epoxy-, (R)-

CAS REGISTRY NUMBER :: 16495-13-9

LAST UPDATED :: 199410

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C10-H12-O2

MOLECULAR WEIGHT :: 164.22

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Mutation test systems - not otherwise specified

TYPE OF TEST :: Cytogenetic analysis

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993

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(S)-苄氧甲基环氧乙烷安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
TX2860030

[ 海关编码 ]:
2910900090

(S)-苄氧甲基环氧乙烷海关

[ 海关编码 ]: 2910900090

[ 中文概述 ]:
2910900090. 三节环环氧化物，环氧醇（酚，醚），包括其卤化，磺化，硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

(S)-苄氧甲基环氧乙烷文献

Bioresolution of benzyl glycidyl ether using whole cells of Bacillus alcalophilus.

J. Basic Microbiol. 52(4) , 383-9, (2012)

The incubation of whole Bacillus alcalophilus cells grown on a mineral supplemented medium (MSM) containing 1% (w/v) sucrose as carbon source, 1.2% (w/v) tryptone as nitrogen source at pH 6.5 and temp...

Metal-mediated cyclization of aryl and benzyl glycidyl ethers: a complete scenario.

J. Am. Chem. Soc. 130(50) , 16838-9, (2008)

Enantiomerically pure aryl and benzyl glycidyl ethers undergo stereospecific cyclizations leading to 3-chromanols or to tetrahydrobenzo[c]oxepin-4-ols under mild conditions in the presence of a cataly...

Enantioselective total synthesis of (+)-gigantecin: exploiting the asymmetric glycolate aldol reaction.

J. Am. Chem. Soc. 126(40) , 12790-1, (2004)

The enantioselective synthesis of the potent, selective, cytotoxic, annonaceous acetogenin, (+)-gigantecin, has been completed. An asymmetric glycolate aldol serves to establish the stereocenters at C...

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