![]() (S)-苄氧甲基环氧乙烷结构式
![]() |
常用名 | (S)-苄氧甲基环氧乙烷 | 英文名 | (S)-(+)-Benzyl glycidyl ether |
---|---|---|---|---|
CAS号 | 16495-13-9 | 分子量 | 164.201 | |
密度 | 1.1±0.1 g/cm3 | 沸点 | 252.7±15.0 °C at 760 mmHg | |
分子式 | C10H12O2 | 熔点 | N/A | |
MSDS | 中文版 美版 | 闪点 | 100.9±19.9 °C | |
符号 |
![]() GHS07 |
信号词 | Warning |
Bioresolution of benzyl glycidyl ether using whole cells of Bacillus alcalophilus.
J. Basic Microbiol. 52(4) , 383-9, (2012) The incubation of whole Bacillus alcalophilus cells grown on a mineral supplemented medium (MSM) containing 1% (w/v) sucrose as carbon source, 1.2% (w/v) tryptone as nitrogen source at pH 6.5 and temperature 30 °C in 24 h kinetically resolved benzyl glycidyl ... |
|
Metal-mediated cyclization of aryl and benzyl glycidyl ethers: a complete scenario.
J. Am. Chem. Soc. 130(50) , 16838-9, (2008) Enantiomerically pure aryl and benzyl glycidyl ethers undergo stereospecific cyclizations leading to 3-chromanols or to tetrahydrobenzo[c]oxepin-4-ols under mild conditions in the presence of a catalytic amount of FeBr3/3AgOTf. The same processes are also med... |
|
Enantioselective total synthesis of (+)-gigantecin: exploiting the asymmetric glycolate aldol reaction.
J. Am. Chem. Soc. 126(40) , 12790-1, (2004) The enantioselective synthesis of the potent, selective, cytotoxic, annonaceous acetogenin, (+)-gigantecin, has been completed. An asymmetric glycolate aldol serves to establish the stereocenters at C13,14 and at C21,22. A Carreira asymmetric acetylide additi... |
|
S. Takano et al.
Tetrahedron Lett. 31 , 3619, (1990)
|
|
R.E. Ireland et al.
J. Org. Chem. 55 , 1423, (1990)
|
|
M. Honda et al.
Chem. Pharm. Bull. 39 , 1385, (1991)
|
|
T.M. Avignon et al.
Tetrahedron 47 , 7279, (1991)
|
|
B.H. Lipshutz et al.
Organic Synth. 69 , 80, (1990)
|
|
S. Takano et al.
Synthesis , 539, (1989)
|
|
J. Chem. Soc. Chem. Commun. , 1371, (1989)
|