氯铂酸铵
氯铂酸铵用途
用作分析试剂,也用于铂海锦的制造
【用途二】
用于反磁性材料或半导体。也用于铂的电镀及制备海绵铂。
氯铂酸铵名称
[ CAS 号 ]:
16919-58-7
[ 中文名 ]:
氯铂酸铵
[ 英文名 ]:
Ammonium chloroplatinate
[中文别名 ]:
[英文别名 ]:
- EINECS 240-973-0
- Ammonium Hexachloroplatinate(IV),Pt Min
- MFCD00010886
- Ammonium platinic chloride
- diazanium,hexachloroplatinum(2-)
- Ammonium hexachloroplatinate
- Diammonium hexachloroplatinate(2-)
- Platinate(2-), hexachloro-, ammonium (1:2)
- Ammonium hexachloroplatinate(IV)
氯铂酸铵物理化学性质
[ 密度 ]:
3.07 g/mL at 25 °C(lit.)
[ 熔点 ]:
°Cd ec.)
[ 分子式 ]:
H8Cl6N2Pt
[ 分子量 ]:
443.87300
[ 精确质量 ]:
440.84700
[ LogP ]:
4.88690
[ 外观性状 ]:
黄色粉末
[ 折射率 ]:
1.95
[ 储存条件 ]:
库房通风低温干燥
[ 水溶解性 ]:
不同温度(℃)时每100毫升水中的溶解克数: 0.289g/0℃;0.374g/10℃;0.499g/20℃;0.637g/30℃;0.815g/40℃ 1.44g/60℃;2.16g/80℃;2.61g/90℃;3.36g/100℃
氯铂酸铵MSDS
氯铂酸铵毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- BP5425000
- CHEMICAL NAME :
- Ammonium chloroplatinate
- CAS REGISTRY NUMBER :
- 16919-58-7
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 25
- MOLECULAR FORMULA :
- Cl6-Pt.2H4-N
- MOLECULAR WEIGHT :
- 443.89
- WISWESSER LINE NOTATION :
- Z&2 PT-G6
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Human
- DOSE/DURATION :
- 900 ng/m3
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - cough Lungs, Thorax, or Respiration - cyanosis
- REFERENCE :
- BJIMAG British Journal of Industrial Medicine. (British Medical Journal, Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year: 2,92,1945
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 195 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 21(7),55,1977
- TYPE OF TEST :
- LC - Lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >565 mg/m3/8H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 23(9),4,1979 *** REVIEWS *** ACGIH TLV-TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,213,1971 OSHA PEL (Gen Indu):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.002 mg(Pt)/m3 (dust) JAN 1993 OEL-AUSTRALIA:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-BELGIUM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-DENMARK:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-FINLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-GERMANY:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-HUNGARY:STEL 0.002 mg(Pt)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-RUSSIA:STEL 0.005 mg/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
氯铂酸铵安全信息
[ 符号 ]:
GHS05, GHS06, GHS08
[ 信号词 ]:
Danger
[ 危害声明 ]:
H301-H317-H318-H334
[ 警示性声明 ]:
P261-P280-P301 + P310-P305 + P351 + P338-P342 + P311
[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
T:Toxic;
[ 风险声明 (欧洲) ]:
R25;R41;R42/43
[ 安全声明 (欧洲) ]:
S22-S26-S36/37/39-S45
[ 危险品运输编码 ]:
UN 3288 6.1/PG 3
[ WGK德国 ]:
1
[ RTECS号 ]:
BP5425000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1
氯铂酸铵文献
ChemPhysChem 16 , 1898-905, (2015)
Renewable energy sources are highly sought after as a result of numerous worldwide problems concerning the environment and the shortage of energy. Currently, the focus in the field is on the developme...
Selective induction of type 2 cytokines following topical exposure of mice to platinum salts.Food Chem. Toxicol. 36(3) , 199-207, (1998)
Repeated topical exposure of BALB/c strain mice to organic chemical respiratory allergens, such as trimellitic anhydride (TMA), or contact allergens such as 2,4-dinitrochlorobenzene (DNCB), provokes c...
Allergy to the complex salts of platinum. A review of the literature and three case reports.Scand. J. Work. Environ. Health 8(2) , 141-5, (1982)
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