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氯铱酸铵

氯铱酸铵用途

【用途一】
用作制备四氯化铱等铱化合物的原料。

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氯铱酸铵名称

[ CAS 号 ]:
16940-92-4

[ 中文名 ]:
氯铱酸铵

[ 英文名 ]:
Ammonium hexachloroiridate(IV)

[中文别名 ]:

[英文别名 ]:

Ammonium Hexachloroiridate(IV)
MFCD00003393
Iridium(IV)-ammonium chloride
Diammonium hexachloroiridate(2-)
Iridate(2-), hexachloro-, diammonium (8CI)
Ammonium chloroiride
Iridate(2-), hexachloro-, ammonium (1:2)
EINECS 241-007-0
diazanium,hexachloroiridium(2-)

氯铱酸铵物理化学性质

[ 密度 ]:
2.86 g/mL at 25 °C(lit.)

[ 分子式 ]:
H₈Cl₆IrN₂

[ 分子量 ]:
441.012

[ 精确质量 ]:
438.844757

[ LogP ]:
4.88940

[ 外观性状 ]:
橄榄色绿色晶体

[ 储存条件 ]:
室温

氯铱酸铵MSDS

详细MSDS(安全技术说明书)

氯铱酸铵毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BP5295000

CHEMICAL NAME :: Ammonium chloroiridate

CAS REGISTRY NUMBER :: 16940-92-4

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C16-Ir.2H4-N

MOLECULAR WEIGHT :: 420.46

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1852 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 21(7),55,1977

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氯铱酸铵安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H312-H332

[ 警示性声明 ]:
P280

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
1759

[ WGK德国 ]:
3

[ RTECS号 ]:
BP5295000

[ 包装等级 ]:
III

[ 危险类别 ]:
8

氯铱酸铵文献

Iridium- and Osmium-decorated Reduced Graphenes as Promising Catalysts for Hydrogen Evolution.

ChemPhysChem 16 , 1898-905, (2015)

Renewable energy sources are highly sought after as a result of numerous worldwide problems concerning the environment and the shortage of energy. Currently, the focus in the field is on the developme...

Insertion of dGMP and dAMP during in vitro DNA synthesis opposite an oxidized form of 7,8-dihydro-8-oxoguanine.

Nucleic Acids Res. 27(2) , 496-502, (1999)

Oxidative damage to DNA bases commonly resultsin the formation of oxidized purines, particularly 7,8-dihydro-8-oxoguanine (8-oxoG) and 7,8-dihydro-8-oxoadenine (8-oxoA), the former being a well-known ...

Proton-coupled electron-transfer oxidation of phenols by hexachloroiridate(IV).

Inorg. Chem. 47(24) , 11458-60, (2008)

One-electron oxidation of phenol, 2,4,6-trimethylphenol, and 2,6-dimethylphenol by [IrCl(6)](2-) in aqueous solution has a simple pH dependence, indicating slow bimolecular oxidation of ArOH and faste...

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