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烯丙基苯基醚

烯丙基苯基醚用途

【用途一】
用于合成药物心得舒及其他精细化工产品

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烯丙基苯基醚名称

[ CAS 号 ]:
1746-13-0

[ 中文名 ]:
丙烯基苯基醚

[ 英文名 ]:
(Allyloxy)benzene

[中文别名 ]:

[英文别名 ]:

Allyl phenyl ether
(Allyloxy)benzene
MFCD00008644
prop-2-enoxybenzene
EINECS 217-125-3

烯丙基苯基醚物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
192.4±9.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₁₀O

[ 分子量 ]:
134.175

[ 闪点 ]:
62.8±0.0 °C

[ 精确质量 ]:
134.073166

[ PSA ]:
9.23000

[ LogP ]:
2.94

[ 外观性状 ]:
透明非常淡黄色液体

[ 蒸汽压 ]:
0.7±0.4 mmHg at 25°C

[ 折射率 ]:
1.504

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开存放

[ 水溶解性 ]:
insoluble

烯丙基苯基醚MSDS

烯丙基苯基醚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DA8575000

CHEMICAL NAME :: Benzene, (2-propenyloxy)-

CAS REGISTRY NUMBER :: 1746-13-0

BEILSTEIN REFERENCE NO. :: 1905622

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C9-H10-O

MOLECULAR WEIGHT :: 134.19

WISWESSER LINE NOTATION :: 1U2OR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 63 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01855 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0737 No. of Facilities: 20 (estimated) No. of Industries: 1 No. of Occupations: 3 No. of Employees: 1929 (estimated) No. of Female Employees: 81 (estimated)

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烯丙基苯基醚安全信息

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
NA 1993 / PGIII

[ WGK德国 ]:
3

[ RTECS号 ]:
DA8575000

[ 海关编码 ]:
2909309090

烯丙基苯基醚合成路线

烯丙基苯基醚上下游产品

烯丙基苯基醚上游产品

烯丙基苯基醚下游产品

烯丙基苯基醚海关

[ 海关编码 ]: 2909309090

[ 中文概述 ]:
2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

烯丙基苯基醚文献

SmI2/water/amine mediates cleavage of allyl ether protected alcohols: application in carbohydrate synthesis and mechanistic considerations.

Org. Lett. 5(22) , 4085-8, (2003)

[reaction: see text]. SmI2/H2O/amine provides selective cleavage of unsubstituted allyl ethers in good to excellent yields. This method is therefore useful in deprotection of alcohols and carbohydrate...

Pd-catalyzed synthesis of allylic silanes from allylic ethers.

Org. Lett. 12(1) , 28-31, (2010)

Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis.

Stereoselective epoxidation of phenyl allyl ether by alkene-utilizing bacteria.

Appl. Microbiol. Biotechnol. 37(1) , 28-31, (1992)

Eighteen newly isolated ethene- and propene-utilizing bacteria were screened for the ability to produce phenyl glycidyl ether, a common precursor for the synthesis of beta blockers, from phenyl allyl ...

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