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2-氯丙酸甲酯

2-氯丙酸甲酯用途

用途一:用作农药、医药、香料的中间体
用途二:α-氯代丙酸甲酯是杀菌剂甲霜灵、苯霜灵和腐霉利,除草剂禾草灵、丙草胺等的中间体。
用途三:用作农药、医药中间体。
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2-氯丙酸甲酯名称

[ CAS 号 ]:
17639-93-9

[ 中文名 ]:
2-氯丙酸甲酯

[ 英文名 ]:
UNII:FDN17EXK1J

[中文别名 ]:

[英文别名 ]:

2-氯丙酸甲酯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
130.8±8.0 °C at 760 mmHg

[ 熔点 ]:
-10 °C

[ 分子式 ]:
C4H7ClO2

[ 分子量 ]:
122.550

[ 闪点 ]:
38.3±0.0 °C

[ 精确质量 ]:
122.013458

[ PSA ]:
26.30000

[ LogP ]:
0.76

[ 外观性状 ]:
透明液体

[ 蒸汽密度 ]:
4.22 (vs air)

[ 蒸汽压 ]:
9.6±0.2 mmHg at 25°C

[ 折射率 ]:
1.409

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开储运

[ 稳定性 ]:
Stable. Flammable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
immiscible

2-氯丙酸甲酯MSDS

2-氯丙酸甲酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UE9100000
CHEMICAL NAME :
Propionic acid, 2-chloro-, methyl ester
CAS REGISTRY NUMBER :
17639-93-9
BEILSTEIN REFERENCE NO. :
1421535
LAST UPDATED :
199710
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C4-H7-Cl-O2
MOLECULAR WEIGHT :
122.56
WISWESSER LINE NOTATION :
GY1&VO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,228,1954
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2-氯丙酸甲酯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R10;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39-S16

[ 危险品运输编码 ]:
UN 2933 3/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
UE9100000

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2915509000

2-氯丙酸甲酯合成路线

2-氯丙酸甲酯上下游产品

2-氯丙酸甲酯制备

其制备方法是将α-氯代丙酸和甲醇在催化剂存在下进行回流反应,反应数小时后经后处理、蒸馏得到产品。
CH3CHClCOOH+CH3OH[催化剂]→CH3CHClCOOCH3+H2O
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2-氯丙酸甲酯海关

[ 海关编码 ]: 2915900090

[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐(酰卤、过氧)化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

2-氯丙酸甲酯文献

Opposite signs of capacitive microsensor signals upon exposure to the enantiomers of methyl propionate compounds.

Angew. Chem. Int. Ed. Engl. 47(5) , 913-6, (2008)

Chiral discrimination of inhalation anesthetics and methyl propionates by thickness shear mode resonators: new insights into the mechanisms of enantioselectivity by cyclodextrins.

Anal. Chem. 69(19) , 4017-31, (1997)

The discrimination of the enantiomers of methyl lactate, methyl 2-chloropropionate, and the inhalation anesthetics enflurane, isoflurane, and desflurane in the gas phase has been performed using thick...

Regulation of Protein Binding Capability of Surfaces via Host-Guest Interactions: Effects of Localized and Average Ligand Density.

Langmuir 31 , 6172-8, (2015)

The protein binding capability of biomaterial surfaces can significantly affect subsequent biological responses, and appropriate ligand presentation is often required to guarantee the best functions. ...


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推荐生产厂家/供应商:

公司名:上海创赛科技有限公司

区域:上海市嘉定区

价格:
¥37.0/25ml ¥71.0/100ml ¥213.0/500ml ¥808.0/2500ml

联系人:夏言

产品详情:[Perfemiker]2-氯丙酸甲酯,98%


公司名:上海阿拉丁生化科技股份有限公司

区域:上海市浦东新区

价格:
¥需询单/1mg ¥需询单/1mg ¥需询单/1mg ¥需询单/1mg

联系人:阿拉丁李高志

产品详情:2-氯丙酸甲酯


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【2-氯丙酸甲酯】化源网提供2-氯丙酸甲酯CAS号17639-93-9,2-氯丙酸甲酯MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询2-氯丙酸甲酯上化源网,专业又轻松。>>电脑版:2-氯丙酸甲酯

标题:2-氯丙酸甲酯_MSDS_用途_密度_CAS号【17639-93-9】_化源网 地址:https://m.chemsrc.com/mip/cas/17639-93-9_951808.html