2-氯丙酸甲酯
2-氯丙酸甲酯用途
用途二:α-氯代丙酸甲酯是杀菌剂甲霜灵、苯霜灵和腐霉利,除草剂禾草灵、丙草胺等的中间体。
用途三:用作农药、医药中间体。
2-氯丙酸甲酯名称
[ CAS 号 ]:
17639-93-9
[ 中文名 ]:
2-氯丙酸甲酯
[ 英文名 ]:
UNII:FDN17EXK1J
[中文别名 ]:
[英文别名 ]:
- Methyl 2-chloropropanoate
- 2-chloropropyl Methyl
- Methyl 2-chloropropi
- Propanoic acid, 2-chloro-, methyl ester
- Mehyl 2-chloropropionate
- EINECS 241-624-5
- α-Chloropropionic acid methyl ester
- 2-Chloropropionic Acid Methyl Ester
- Methyl α-chloropropionate
- 2-Chlorpropionsuremethylester
2-氯丙酸甲酯物理化学性质
[ 密度 ]:
1.1±0.1 g/cm3
[ 沸点 ]:
130.8±8.0 °C at 760 mmHg
[ 熔点 ]:
-10 °C
[ 分子式 ]:
C4H7ClO2
[ 分子量 ]:
122.550
[ 闪点 ]:
38.3±0.0 °C
[ 精确质量 ]:
122.013458
[ PSA ]:
26.30000
[ LogP ]:
0.76
[ 外观性状 ]:
透明液体
[ 蒸汽密度 ]:
4.22 (vs air)
[ 蒸汽压 ]:
9.6±0.2 mmHg at 25°C
[ 折射率 ]:
1.409
[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开储运
[ 稳定性 ]:
Stable. Flammable. Incompatible with strong oxidizing agents.
[ 水溶解性 ]:
immiscible
2-氯丙酸甲酯MSDS
2-氯丙酸甲酯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UE9100000
- CHEMICAL NAME :
- Propionic acid, 2-chloro-, methyl ester
- CAS REGISTRY NUMBER :
- 17639-93-9
- BEILSTEIN REFERENCE NO. :
- 1421535
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C4-H7-Cl-O2
- MOLECULAR WEIGHT :
- 122.56
- WISWESSER LINE NOTATION :
- GY1&VO1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 250 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,228,1954
2-氯丙酸甲酯安全信息
[ 符号 ]:
GHS02, GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H226-H315-H319-H335
[ 警示性声明 ]:
P261-P305 + P351 + P338
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
Xi:Irritant
[ 风险声明 (欧洲) ]:
R10;R36/37/38
[ 安全声明 (欧洲) ]:
S26-S36-S37/39-S16
[ 危险品运输编码 ]:
UN 2933 3/PG 3
[ WGK德国 ]:
1
[ RTECS号 ]:
UE9100000
[ 包装等级 ]:
III
[ 危险类别 ]:
3
[ 海关编码 ]:
2915509000
2-氯丙酸甲酯合成路线
2-氯丙酸甲酯上下游产品
2-氯丙酸甲酯上游产品
2-氯丙酸甲酯下游产品
2-氯丙酸甲酯制备
CH3CHClCOOH+CH3OH[催化剂]→CH3CHClCOOCH3+H2O
2-氯丙酸甲酯海关
[ 海关编码 ]: 2915900090
[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐(酰卤、过氧)化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单
[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
2-氯丙酸甲酯文献
Angew. Chem. Int. Ed. Engl. 47(5) , 913-6, (2008)
Chiral discrimination of inhalation anesthetics and methyl propionates by thickness shear mode resonators: new insights into the mechanisms of enantioselectivity by cyclodextrins.
Anal. Chem. 69(19) , 4017-31, (1997)
The discrimination of the enantiomers of methyl lactate, methyl 2-chloropropionate, and the inhalation anesthetics enflurane, isoflurane, and desflurane in the gas phase has been performed using thick...
Regulation of Protein Binding Capability of Surfaces via Host-Guest Interactions: Effects of Localized and Average Ligand Density.Langmuir 31 , 6172-8, (2015)
The protein binding capability of biomaterial surfaces can significantly affect subsequent biological responses, and appropriate ligand presentation is often required to guarantee the best functions. ...
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