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1-环己烯-1-甲酸甲酯

1-环己烯-1-甲酸甲酯名称

[ CAS 号 ]:
18448-47-0

[ 中文名 ]:
1-环己烯基-1-甲酸甲酯

[ 英文名 ]:
Methyl 1-cyclohexene-1-carboxylate

[中文别名 ]:

[英文别名 ]:

Methyl cyclohex-1-enecarboxylate
1-Cyclohexene-1-carboxylic acid,methyl ester
Methyl 1-Cyclohexenecarboxylate
Methyl 1-cyclohexene-1-carboxylate
1-Cyclohexen-1-carbonsaeure-methylester
methyl cyclohexenecarboxylate
cyclohex-1-enecarboxylic acid methyl ester
Methyl cyclohex-1-ene-1-carboxylate
MFCD00001544
cyclohexene-1-carboxylic acid methyl ester

1-环己烯-1-甲酸甲酯物理化学性质

[ 密度 ]:
1.028 g/mL at 20 °C(lit.)

[ 沸点 ]:
190-192 °C

[ 分子式 ]:
C₈H₁₂O₂

[ 分子量 ]:
140.18000

[ 闪点 ]:
165 °F

[ 精确质量 ]:
140.08400

[ PSA ]:
26.30000

[ LogP ]:
1.65980

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
0.463mmHg at 25°C

[ 折射率 ]:
n20/D 1.477

[ 储存条件 ]:
室温

[ 水溶解性 ]:
insoluble

1-环己烯-1-甲酸甲酯MSDS

1-环己烯-1-甲酸甲酯安全信息

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 安全声明 (欧洲) ]:
S23-S24/25

[ WGK德国 ]:
3

[ 海关编码 ]:
2916209090

1-环己烯-1-甲酸甲酯合成路线

1-环己烯-1-甲酸甲酯上下游产品

1-环己烯-1-甲酸甲酯上游产品

1-环己烯-1-甲酸甲酯下游产品

1-环己烯-1-甲酸甲酯海关

[ 海关编码 ]: 2916209090

[ 中文概述 ]:
2916209090 其他（环烷、环烯、环萜烯）一元羧酸（包括酸酐、酰卤化物，过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

1-环己烯-1-甲酸甲酯文献

Ceric ammonium nitrate (CAN)-mediated oxidative cycloaddition of 1, 3-dicarbonyls to conjugated compounds. Efficient synthesis of dihydrofurans, dihydrofurocoumarins, dihydrofuroquinolinones, dihydrofurophenalenones, and furonaphthoquinone natural products. Lee YR, et al.

Tetrahedron 56(45) , 8845-53, (2000)

Diastereoselective Synthesis of cis-1, 2-Dialkenylcyclopropanols and Subsequent Oxy-Cope Rearrangement. Lee J, et al.

J. Am. Chem. Soc. 117(39) , 9919-20, (1995)

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