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肉桂腈

肉桂腈用途

【用途一】
肉桂腈是一种极其稳定的腈基香料，香气很象天然肉桂。

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肉桂腈名称

[ CAS 号 ]:
1885-38-7

[ 中文名 ]:
肉桂腈

[ 英文名 ]:
trans-Cinnamonitrile

[中文别名 ]:

[英文别名 ]:

Cinnamonitrile
3-phenylacrylonitrile
EINECS 217-552-5
(E)-3-Phenylacrylonitrile
2-Propenenitrile, 3-phenyl-, (E)-
trans-cinnamonitrile
trans-3-Phenyl-2-propenenitrile
CINNAMALVA
(2E)-3-phenylprop-2-enenitrile
trans-β-Phenylacrylonitrile

肉桂腈物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
263.8±0.0 °C at 760 mmHg

[ 熔点 ]:
18-20 °C(lit.)

[ 分子式 ]:
C₉H₇N

[ 分子量 ]:
129.159

[ 闪点 ]:
105.2±11.2 °C

[ 精确质量 ]:
129.057846

[ PSA ]:
23.79000

[ LogP ]:
2.32

[ 外观性状 ]:
透明无色至黄色液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.595

[ 储存条件 ]:
室温

[ 水溶解性 ]:
insoluble

肉桂腈MSDS

肉桂腈安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
3276

[ WGK德国 ]:
3

[ RTECS号 ]:
UD1440000

[ 包装等级 ]:
I; II; III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2926909090

肉桂腈合成路线

肉桂腈上下游产品

肉桂腈上游产品

肉桂腈下游产品

肉桂腈制备

桂醛与盐酸羟胺在吡啶存在下经加成-消除反应生成醛肟，再与甲苯共沸脱水即得肉桂腈

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肉桂腈海关

[ 海关编码 ]: 2926909090

[ 中文概述 ]:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

肉桂腈文献

The spectroscopy and photochemistry of quinioline structural isomers: (E)- and (Z)-phenylvinylnitrile.

J. Chem. Phys. 143 , 074304, (2015)

In Titan's atmosphere, photochemical pathways that lead to nitrogen heteroaromatics may incorporate photoisomerization of their structural isomers as a final step. (E)- and (Z)-phenylvinylnitrile ((E)...

Reversible targeting of noncatalytic cysteines with chemically tuned electrophiles.

Nat. Chem. Biol. 8 , 471-6, (2012)

Targeting noncatalytic cysteine residues with irreversible acrylamide-based inhibitors is a powerful approach for enhancing pharmacological potency and selectivity. Nevertheless, concerns about off-ta...

Formation of mercapturic acids from acrylonitrile, crotononitrile, and cinnamonitrile by direct conjugation and via an intermediate oxidation process.

Drug Metab. Dispos. 9(3) , 246-9, (1981)

After administration of acrylonitrile, crotononitrile and cinnamonitrile to rats, two types of mercapturic acids were isolated from urine and identified by mass and NMR spectroscopy as N-acetyl-S-(2-c...

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肉桂腈