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正癸胺

正癸胺用途

用于有机合成，也用作溶剂

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正癸胺名称

[ CAS 号 ]:
2016-57-1

[ 中文名 ]:
1-氨基癸烷

[ 英文名 ]:
decanamine

[中文别名 ]:

[英文别名 ]:

1-Decanamine
1-decanoyloxypropan-2-one
n-decyl-amine
n-1-decylamine
MFCD00008149
Decan-1-amine
decyl amine
decylamine
1-Aminodecane,NDA
1-decanylamine

正癸胺物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
221.4±3.0 °C at 760 mmHg

[ 熔点 ]:
12-14 °C(lit.)

[ 分子式 ]:
C₁₀H₂₃N

[ 分子量 ]:
157.296

[ 闪点 ]:
85.6±0.0 °C

[ 精确质量 ]:
157.183044

[ PSA ]:
26.02000

[ LogP ]:
4.12

[ 外观性状 ]:
透明非常淡黄色液体

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.439

[ 储存条件 ]:
室温

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides. Absorbs carbon dioxide from the air.

正癸胺MSDS

正癸胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: HD6475000

CHEMICAL NAME :: 1-Decanamine

CAS REGISTRY NUMBER :: 2016-57-1

BEILSTEIN REFERENCE NO. :: 1735220

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C10-H23-N

MOLECULAR WEIGHT :: 157.34

WISWESSER LINE NOTATION :: Z10

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 280 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 71 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique. (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France) V.9- 1974- Volume(issue)/page/year: 26,517,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 350 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

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正癸胺安全信息

[ 符号 ]:

GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311-H314-H400

[ 警示性声明 ]:
P273-P280-P301 + P310-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R20/22;R24;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2922 8/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
HD6475000

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2921199090

正癸胺合成路线

正癸胺上下游产品

正癸胺上游产品

正癸胺下游产品

正癸胺制备

以癸酸为原料，硅胶为催化剂，在380-400℃下通氨反应得癸腈，经水洗、分层、干燥、精馏，得精癸腈。然后以镍铝为催化剂，在80℃，1.96MPa压力下加氢，至不吸氢为止，增大压力至2.35MPa，保持反应3h，放冷后放出混合物，滤去催化剂，分馏，收集199-221℃馏分，可得癸胺和副产的二癸胺，还有少量三癸胺。

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正癸胺海关

[ 海关编码 ]: 2921199090

[ 中文概述 ]:
2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

正癸胺文献

Validation of a general method for activity estimation of cyanide evolving oxidoreductases.

Anal. Biochem. 471 , 44-50, (2015)

Ethylene is a key molecule in organic synthesis currently produced by steam cracking of fossil hydrocarbons. In nature, ethylene is produced in higher plants by 1-aminocyclopropane-1-carboxylic acid o...

Use of a standardized JaCVAM in vivo rat comet assay protocol to assess the genotoxicity of three coded test compounds; ampicillin trihydrate, 1,2-dimethylhydrazine dihydrochloride, and N-nitrosodimethylamine.

Mutat. Res. Genet. Toxicol. Environ. Mutagen. 786-788 , 158-64, (2015)

As part of the Japanese Center for the Validation of Alternative Methods (JaCVAM)-initiative international validation study of the in vivo rat alkaline comet assay (comet assay), our laboratory examin...

Myristic acid potentiates palmitic acid-induced lipotoxicity and steatohepatitis associated with lipodystrophy by sustaning de novo ceramide synthesis.

Oncotarget 6 , 41479-96, (2015)

Palmitic acid (PA) induces hepatocyte apoptosis and fuels de novo ceramide synthesis in the endoplasmic reticulum (ER). Myristic acid (MA), a free fatty acid highly abundant in copra/palmist oils, is ...

更多文献

正癸胺

正癸胺用途

正癸胺名称

正癸胺物理化学性质

正癸胺MSDS

详细MSDS(安全技术说明书)

正癸胺毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

正癸胺安全信息

正癸胺合成路线

详细合成路线

正癸胺上下游产品

正癸胺上游产品

正癸胺下游产品

正癸胺制备

正癸胺海关

正癸胺文献

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