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2-碘苯乙酮

2-碘苯乙酮名称

[ CAS 号 ]:
2142-70-3

[ 中文名 ]:
2'-碘苯乙酮

[ 英文名 ]:
2'-Iodoacetophenone

[中文别名 ]:

2-碘苯乙酮

[英文别名 ]:

1-(2-iodophenyl)ethan-1-one
2-IC6H4COMe
2′-Iodoacetophenone
MFCD00094998
2-Ac-C6H4-I
2‘-Iodoacetophenone
o-Iodoacetophenone
ortho-iodoacetophenone
2'-Iodoacetophenone
2-Iodoacetophenone

2-碘苯乙酮物理化学性质

[ 密度 ]:
1.72 g/mL at 25 °C(lit.)

[ 沸点 ]:
139-140°C 12mm

[ 分子式 ]:
C₈H₇IO

[ 分子量 ]:
246.04500

[ 闪点 ]:
218 °F

[ 精确质量 ]:
245.95400

[ PSA ]:
17.07000

[ LogP ]:
2.49380

[ 外观性状 ]:
透明黄色液体

[ 蒸汽压 ]:
0.00779mmHg at 25°C

[ 折射率 ]:
n20/D 1.618(lit.)

[ 储存条件 ]:
室温，密封，干燥

2-碘苯乙酮MSDS

2-碘苯乙酮安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
C: Corrosive;

[ 风险声明 (欧洲) ]:
R36/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2914700090

2-碘苯乙酮合成路线

2-碘苯乙酮上下游产品

2-碘苯乙酮上游产品

2-碘苯乙酮下游产品

2-碘苯乙酮海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

2-碘苯乙酮文献

Trapping evidence for the thermal cyclization of di-(o-acetylphenyl)acetylene to 3,3'-dimethyl-1,1'-biisobenzofuran.

Beilstein J. Org. Chem. 1(1) , 18, (2005)

The reaction of di-(o-acetylphenyl)acetylene (1) with excess dimethyl acetylenedicarboxylate (DMAD) produced bis-DMAD adducts meso-3 and rac-3. This transformation is suggested to involve thermal rear...

Cobalt-catalyzed regioselective carbocyclization reaction of o-iodophenyl ketones and aldehydes with alkynes, acrylates, and acrylonitrile: a facile route to indenols and indenes.

J. Org. Chem. 69(14) , 4781-7, (2004)

An efficient cobalt-catalyzed carbocylization for the synthesis of indenols and indenes and a new method for reductive decyanation are described. 2-Iodophenyl ketones and aldehydes 1a-g undergo carboc...

Cobalt-Catalyzed Carbocyclization of o-Iodobenzaldehydes and o-Iodophenylketones with Alkynes. Chang KJ, et al.

Org. Lett. 5(21) , 3963-3966, (2003)

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