2-碘苯乙酮
2-碘苯乙酮结构式
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常用名 | 2-碘苯乙酮 | 英文名 | 2'-Iodoacetophenone |
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| CAS号 | 2142-70-3 | 分子量 | 246.04500 | |
| 密度 | 1.72 g/mL at 25 °C(lit.) | 沸点 | 139-140°C 12mm | |
| 分子式 | C8H7IO | 熔点 | N/A | |
| MSDS | N/A | 闪点 | 218 °F |
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Trapping evidence for the thermal cyclization of di-(o-acetylphenyl)acetylene to 3,3'-dimethyl-1,1'-biisobenzofuran.
Beilstein J. Org. Chem. 1(1) , 18, (2005) The reaction of di-(o-acetylphenyl)acetylene (1) with excess dimethyl acetylenedicarboxylate (DMAD) produced bis-DMAD adducts meso-3 and rac-3. This transformation is suggested to involve thermal rearrangement of 1 to the intermediate 3,3'-dimethyl-1,1'-biiso... |
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Cobalt-catalyzed regioselective carbocyclization reaction of o-iodophenyl ketones and aldehydes with alkynes, acrylates, and acrylonitrile: a facile route to indenols and indenes.
J. Org. Chem. 69(14) , 4781-7, (2004) An efficient cobalt-catalyzed carbocylization for the synthesis of indenols and indenes and a new method for reductive decyanation are described. 2-Iodophenyl ketones and aldehydes 1a-g undergo carbocyclization with various disubstituted alkynes 2a-k in the p... |
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Cobalt-Catalyzed Carbocyclization of o-Iodobenzaldehydes and o-Iodophenylketones with Alkynes. Chang KJ, et al.
Org. Lett. 5(21) , 3963-3966, (2003)
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