1-甲氧基-1,3-环己二烯

1-甲氧基-1,3-环己二烯名称

[ CAS 号 ]:
2161-90-2

[ 中文名 ]:
1-甲氧基-1,3-环己二烯

[ 英文名 ]:
1-methoxycyclohexa-1,3-diene

[英文别名 ]:

1-Methoxy-1,3-cyclohexadiene
Dihydroanisole
EINECS 218-483-3
Cyclohexadiene,1-methoxy
1-methoxycyclohexyl-1,3-diene
1-methyoxy-1,3-cyclohexadiene
1,3-Cyclohexadiene,1-methoxy
1-Methoxycyclohexadiene
1-methoxy-cyclohexa-1,3-diene
MFCD00001533

1-甲氧基-1,3-环己二烯物理化学性质

[ 密度 ]:
0.93g/cm3

[ 沸点 ]:
143.8ºC at 760mmHg

[ 分子式 ]:
C₇H₁₀O

[ 分子量 ]:
110.15400

[ 闪点 ]:
51.1ºC

[ 精确质量 ]:
110.07300

[ PSA ]:
9.23000

[ LogP ]:
1.86670

[ 蒸汽压 ]:
6.61mmHg at 25°C

[ 折射率 ]:
n20/D 1.488(lit.)

1-甲氧基-1,3-环己二烯MSDS

1-甲氧基-1,3-环己二烯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H302 + H312 + H332

[ 警示性声明 ]:
P280

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn: Harmful;

[ 风险声明 (欧洲) ]:
10-20/21/22

[ 安全声明 (欧洲) ]:
16-33-36/37/39

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

[ 海关编码 ]:
2909209000

1-甲氧基-1,3-环己二烯合成路线

1-甲氧基-1,3-环己二烯上下游产品

1-甲氧基-1,3-环己二烯上游产品

1-甲氧基-1,3-环己二烯下游产品

1-甲氧基-1,3-环己二烯海关

[ 海关编码 ]: 2909209000

[ 中文概述 ]:
2909209000 环烷醚、环烯醚〔包括其卤化,磺化,硝化或亚硝化衍生物及环萜烯醚的上述衍生物〕。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ Summary ]:
2909209000 other cyclanic, cyclenic or cyclotherpenic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

1-甲氧基-1,3-环己二烯文献

Remote Regiocontrol by a Thioether Group in Diels-Alder Reactions of Naphthazarin: Regioselective Access to Tetracyclic Polyhydroxyquinones.

J. Org. Chem. 61(18) , 6136-6138, (1996)

The synthesis of tetracyclic polyhydroxyquinones 5a and 5b was achieved through a sequence involving two Diels-Alder reactions with 1-methoxy-1,3-cyclohexadiene: the first with 2-(p-tolylthio)naphthaz...

Synthesis of tetra-ortho-substituted, phosphorus-containing and carbonyl-containing biaryls utilizing a Diels-Alder approach.

J. Am. Chem. Soc. 129(29) , 9109-16, (2007)

The application of the Diels-Alder approach to biaryls (DAB) is described for the synthesis of tetra-ortho-substituted biaryl compounds containing orthogonally functionalized substituents. The synthes...

Diels-Alder approach to biaryls (DAB): importance of the ortho-nitro moiety in the [4 + 2] cycloaddition.

Org. Biomol. Chem. 6(2) , 255-7, (2008)

A series of nitrophenyl acetylenes were evaluated for their utility in a cycloaddition-cycloreversion approach to polysubstituted biaryls. ortho-Nitrophenyl acetylene consistently provided the target ...

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