1-(4-甲基-2-硝基苯基偶氮)-2-萘酚
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚用途
用于油墨、油漆、文教用品的着色
【用途二】
用于塑料、橡胶制品、文教用品、涂料印花等的着色
【用途三】
可用于印泥、印油铅笔、蜡笔、水彩和油彩颜料以及橡胶制品的着色；也适用于漆布、涂料、塑料和天然生漆以及涂刷沙管、工艺美术品和化妆品的着色。
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚名称
[ CAS 号 ]:
2425-85-6
[ 中文名 ]:
甲苯胺红
[ 英文名 ]:
Pigment Red 3
[中文别名 ]:
[英文别名 ]:
- hansaredb
- Toluidine Red
- <2-Nitro-4-methyl-benzolazo>-naphthol-(2)
- EINECS 219-372-2
- hansaredg
- AKA221
- PR 3
- pigment red percent3
- fastredr
- 1-(4-Methyl-2-nitro-phenylazo)-[2]naphthol
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚物理化学性质
[ 密度 ]:
1.32 g/cm3
[ 沸点 ]:
543.5ºC at 760 mmHg
[ 熔点 ]:
270-272 °C(lit.)
[ 分子式 ]:
C17H13N3O3
[ 分子量 ]:
307.30300
[ 精确质量 ]:
307.09600
[ PSA ]:
90.77000
[ LogP ]:
5.70060
[ 外观性状 ]:
红色至橙色粉末
[ 蒸汽压 ]:
8.02E-10mmHg at 25°C
[ 折射率 ]:
1.66
[ 储存条件 ]:
室温，干燥
[ 稳定性 ]:
Stable. May be moisture sensitive. Incompatible with strong oxidizing agents.
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚MSDS
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- QK4247000
- CHEMICAL NAME :
- 2-Naphthalenol, 1-((4-methyl-2-nitrophenyl)azo)-
- CAS REGISTRY NUMBER :
- 2425-85-6
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 16
- MOLECULAR FORMULA :
- C17-H13-N3-O3
- MOLECULAR WEIGHT :
- 307.33
- WISWESSER LINE NOTATION :
- L66J BNUNR D1 BNW& CQ
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 42 gm/kg/14D-C
- TOXIC EFFECTS :
- Blood - normocytic anemia Blood - changes in other cell count (unspecified)
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 68 gm/kg/90D-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight Blood - changes in bone marrow (not otherwise specified)
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 84 gm/kg/2W-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - other changes
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 273 gm/kg/13W-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Related to Chronic Data - death
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 910 gm/kg/2Y-C
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Liver - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 4368 gm/kg/2Y-C
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Liver - tumors Kidney, Ureter, Bladder - tumors
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- DOSE/DURATION :
- 3333 ug/plate
- REFERENCE :
- ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 8(Suppl 7),1,1986 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,259,1993 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,259,1993 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,259,1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2109 No. of Facilities: 6944 (estimated) No. of Industries: 78 No. of Occupations: 56 No. of Employees: 47730 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2109 No. of Facilities: 4689 (estimated) No. of Industries: 57 No. of Occupations: 53 No. of Employees: 51931 (estimated) No. of Female Employees: 11615 (estimated)
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚安全信息
[ 符号 ]:
GHS05, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H318-H410
[ 警示性声明 ]:
P273-P280-P305 + P351 + P338-P501
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful
[ 风险声明 (欧洲) ]:
R40
[ 安全声明 (欧洲) ]:
S26-S39-S60-S61
[ 危险品运输编码 ]:
UN 3077 9/PG 3
[ RTECS号 ]:
QK4247000
[ 海关编码 ]:
2927000090
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚合成路线
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚上下游产品
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚上游产品
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚下游产品
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚制备
1.将红色基GL（邻硝基对甲苯胺）重氮化后，与2-萘酚钠盐进行偶事，再经过滤；干燥；粉碎等处理过程而制得产品。1.重氮化2.2-萘酚钠盐制备3.偶合产品要求色光与标准品近似，着色力为标准品的100±5（分），水分含量≤1%，吸油量45±5%，耐晒性7级，耐热性180℃，耐酸性及耐碱性均为3级，水渗性及乙醇渗性均为2级，油渗透性及石蜡渗透性均为1-2级，细度（痛过60目筛余物含量）≤5%。原料消耗（kg、t）红色基GL（100%） 5202-萘酚（100%） 500亚硝酸钠（工业） 235盐酸（31%） 1310纯碱（工业） 200烧碱（100%） 175碳酸氢钠 460拉开粉 15太古油 30活性炭22.
2.主要采用重氮偶合法。以邻硝基对甲苯胺 （ 红色基GL）为原料，先进行重氮化反应，然后与2-萘酚在碱性条件下进行偶合反应，再经过滤、干燥、粉碎等过程而制得。
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚海关
[ 海关编码 ]: 2927000090
[ 中文概述 ]:
2927000090 其他重氮化合物、偶氮化合物等（包括氧化偶氮化合物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%
1-(4-甲基-2-硝基苯基偶氮)-2-萘酚文献
IARC Monogr. Eval. Carcinog. Risks Hum. 57 , 259-67, (1993)
14-day and 90-day toxicity studies of C.I. Pigment Red 3 in Fischer 344 rats and B6C3F1 mice.
Food Chem. Toxicol. 27(12) , 793-800, (1989)
Treatment of F344 rats and B6C3F1 mice with C.I. Pigment Red 3 in the diet (10, 5.0, 2.5, 1.25, 0.6 or 0.3%) for 14 and 90 days resulted in haematological alterations consistent with haemolytic anaemi...
Interlaboratory comparison of the toluidine red unheated serum test antigen preparation.J. Clin. Microbiol. 20(3) , 434-7, (1984)
The toluidine red unheated serum test (TRUST) antigen, a macroscopic flocculation test antigen developed by Pettit et al. (J. Clin. Microbiol. 18:1141-1145, 1983) by modifying the color-coded antigen ...
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海化源世纪贸易有限公司
区域：上海市普陀区
价格：
联系人：徐经理
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥1399.9/100g
￥83.9/1g
￥661.9/25g
￥2999.9/500g
联系人：阿拉丁
公司名：上海创赛科技有限公司
区域：上海市嘉定区
价格：
￥117.0/1g
￥457.0/5g
￥897.0/25g
联系人：夏言
产品详情：[Perfemiker]1-(4-甲基-2-硝基苯基偶氮)-2-萘酚,≥98%
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相关化合物
[1-(4-甲基-2-硝基苯基偶氮)-2-萘酚]化源网提供1-(4-甲基-2-硝基苯基偶氮)-2-萘酚CAS号2425-85-6，1-(4-甲基-2-硝基苯基偶氮)-2-萘酚MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询1-(4-甲基-2-硝基苯基偶氮)-2-萘酚上化源网，专业又轻松。>>电脑版：1-(4-甲基-2-硝基苯基偶氮)-2-萘酚
标题：2425-85-6_1-(4-甲基-2-硝基苯基偶氮)-2-萘酚CAS号:2425-85-6_1-(4-甲基-2-硝基苯基偶氮)-2-萘酚【结构式 性质 英文】 - 化源网 地址：https://m.chemsrc.com/mip/cas/2425-85-6_749619.html