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(S)-1-苯基-1,2-乙二醇

(S)-1-苯基-1,2-乙二醇用途

【用途一】
合成手性精细化学品中间体。

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(S)-1-苯基-1,2-乙二醇名称

[ CAS 号 ]:
25779-13-9

[ 中文名 ]:
(S)-(+)-1-苯基-1,2-乙二醇

[ 英文名 ]:
styrene glycol

[中文别名 ]:

[英文别名 ]:

(S)-(+)-1-Phenylethane-1,2-diol
MFCD00066256
(1S)-1-Phenyl-1,2-ethanediol
(S)-(+)-Styrene Glycol
1,2-Ethanediol, 1-phenyl-
1-Phenyl-1,2-ethanediol
(S)-(+)-1-Phenyl-1,2-ethanediol
1,2-Ethanediol, 1-phenyl-, (1S)-
(S)-1-Phenylethane-1,2-diol
styrene glycol

(S)-1-苯基-1,2-乙二醇物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
273.5±0.0 °C at 760 mmHg

[ 熔点 ]:
65-68ºC

[ 分子式 ]:
C₈H₁₀O₂

[ 分子量 ]:
138.164

[ 闪点 ]:
145.7±16.4 °C

[ 精确质量 ]:
138.068085

[ PSA ]:
40.46000

[ LogP ]:
0.04

[ 外观性状 ]:
白色至淡黄色晶体粉末

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.573

[ 储存条件 ]:
室温

(S)-1-苯基-1,2-乙二醇MSDS

(S)-1-苯基-1,2-乙二醇安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi,T

[ 风险声明 (欧洲) ]:
R23/24/25

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2906299090

(S)-1-苯基-1,2-乙二醇合成路线

(S)-1-苯基-1,2-乙二醇上下游产品

(S)-1-苯基-1,2-乙二醇上游产品

(S)-1-苯基-1,2-乙二醇下游产品

(S)-1-苯基-1,2-乙二醇海关

[ 海关编码 ]: 2906299090

[ 中文概述 ]:
2906299090 其他芳香醇. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2906299090 other aromatic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

(S)-1-苯基-1,2-乙二醇文献

Enhancement of Candida parapsilosis catalyzing deracemization of (R,S)-1-phenyl-1,2-ethanediol to its (S)-enantiomer by a highly productive "two-in-one" resin-based in situ product removal strategy.

Bioresour. Technol. 101(21) , 8461-3, (2010)

In this study, a highly efficient process for Candida parapsilosis-catalyzed deracemization of racemic 1-phenyl-1,2-ethanediol (PED) was described, based on a resin-based in situ substrate feeding and...

Biosynthesis of (R)-phenyl-1,2-ethanediol from racemic styrene oxide by using bacterial and marine fish epoxide hydrolases.

Biotechnol. Lett. 30(1) , 127-33, (2008)

Enantio-convergent hydrolysis of racemic styrene oxides was achieved to prepare enantiopure (R)-phenyl-1,2-ethanediol by using two recombinant epoxide hydrolases (EHs) of a bacterium, Caulobacter cres...

Efficient one-step production of (S)-1-phenyl-1,2-ethanediol from (R)-enantiomer plus NAD(+)-NADPH in-situ regeneration using engineered Escherichia coli.

Microb. Cell Fact. 11 , 167, (2012)

Candida parapsilosis CCTCC M203011 catalyzes the stereoinversion of (R)-1-phenyl-1,2-ethanediol (PED) through oxidation and reduction. Its NAD(+)-linked (R)-carbonyl reductase (RCR) catalyzes the oxid...

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