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异丙氧磷

异丙氧磷用途

丙氨磷是一种有机磷杀虫剂。Propetamphos引起细胞毒性和氧化应激[1][2]。
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异丙氧磷名称

[ CAS 号 ]:
31218-83-4

[ 中文名 ]:
胺丙畏

[ 英文名 ]:
Tsar

[中文别名 ]:

[英文别名 ]:

异丙氧磷生物活性

[ 描述 ]:

丙氨磷是一种有机磷杀虫剂。Propetamphos引起细胞毒性和氧化应激[1][2]。

[ 相关类别 ]:

研究领域 >> 感染
信号通路 >> 其他 >> 其他

[体内研究]

蜂胶(100 mg/kg/天；口服；28天) 对由 丙烯磷诱导的 Wistar白化大鼠表现出抗自由基和抗氧化作用[1]

[参考文献]

[1]. Kanbur M, et al. Antioxidant effect of propolis against exposure to propetamphos in rats. Ecotoxicol Environ Saf. 2009 Mar;72(3):909-15.  

[2]. Cetin E, et al. Propetamphos-induced changes in haematological and biochemical parameters of female rats: protective role of propolis. Food Chem Toxicol. 2010 Jul;48(7):1806-10.  

异丙氧磷物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
321.1±44.0 °C at 760 mmHg

[ 熔点 ]:
<25℃

[ 分子式 ]:
C10H20NO4PS

[ 分子量 ]:
281.31

[ 闪点 ]:
148.0±28.4 °C

[ 精确质量 ]:
281.085052

[ PSA ]:
98.69000

[ LogP ]:
1.61

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.495

[ 储存条件 ]:
APPROX 4°C

异丙氧磷MSDS

详细MSDS(安全技术说明书)

异丙氧磷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GQ4750000
CHEMICAL NAME :
Crotonic acid, 3-hydroxy-, isopropyl ester, O-ester with O-methyl ethylphosphoramidothioate, (E)-
CAS REGISTRY NUMBER :
31218-83-4
LAST UPDATED :
199706
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C10-H20-N-O4-P-S
MOLECULAR WEIGHT :
281.34

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
62400 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 37,1621,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
564 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 35,1315,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
49 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 34,79,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
130 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PSTDAN Pesticides. (Colour Pub. Pvt. Ltd., 126-A Dhuruwadi, Off Dr. Nariman Rd., Bombay 400-025, India) V.1- 1967- Volume(issue)/page/year: 15(10),37,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
4 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PSTDAN Pesticides. (Colour Pub. Pvt. Ltd., 126-A Dhuruwadi, Off Dr. Nariman Rd., Bombay 400-025, India) V.1- 1967- Volume(issue)/page/year: 15(10),37,1981 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2243 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 6 (estimated)
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异丙氧磷安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311-H330-H410

[ 警示性声明 ]:
P260-P273-P280-P284-P301 + P310 + P330-P304 + P340 + P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T: Toxic;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R25

[ 安全声明 (欧洲) ]:
S37;S45;S60;S61

[ 危险品运输编码 ]:
UN 3018

[ RTECS号 ]:
GQ4750000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2931900090

异丙氧磷制备

1、 在催化剂、缚酸剂存在下，由3-羟基丁烯酸异丙酯与硫代磷酰氯反应得到的中间体，再与甲醇、乙胺缩合制得烯虫磷。工业生产中，将三丁胺加入乙酰乙酸异丙酯和硫代磷酰氯的混合物中，加料时搅拌冷却-3℃，继续在0-3℃搅拌4.5h，分离粘稠油状液体，加甲苯、石油醚，滤去三丁基氯化铵，滤液在浴温30℃下真空浓缩，残存物中加入甲醇，尽可能快地降至0℃，搅拌4h，再加入70%乙胺的水溶液，加料温度-5℃，混合在0℃搅拌4.5h。反应混合物用约10%盐酸溶液提取两次，第二次提取时加入石油醚有利于提取，石油醚再用水洗、碱洗，用无水硫酸钠干燥，除去溶剂，得烯虫磷。原料消耗定额：三丁胺670kg/t、乙酰乙酸异丙酯520kg/t、硫代磷酰氯650kg/t、甲醇470kg/t、乙胺（70%）820kg/t。

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异丙氧磷海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

异丙氧磷文献

Activated transformations of organophosphorus insecticides in the case of non-AChE inhibitory oxons.

Pest Manag. Sci. 58(11) , 1107-17, (2002)

Many organophosphorus (OP) compounds are of the thiono form and in insects or animals are converted by microsomal mixed function oxidases (MFO) into the oxon forms which inhibit acetylcholinesterase (...

Insecticide susceptibility of cat flea (Siphonaptera: Pulicidae) pupae.

J. Econ. Entomol. 89(2) , 421-7, (1996)

Studies were conducted to investigate what protective nature the cocoon and nylon carpeting has against the performance of insecticides directed at cat flea, Ctenocephalides felis (Bouché), pupae deve...

Survey of levels of propetamphos and diazinon used to control sheep scab in Northern Ireland.

Vet. Rec. 126(11) , 263-5, (1990)

As a result of an increase in the incidence of sheep scab in Northern Ireland, the concentrations of propetamphos and diazinon were measured during 1987 and 1988 in fleece and liquid dip samples from ...


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