磺草灵
磺草灵用途
磺草灵名称
[ CAS 号 ]:
3337-71-1
[ 中文名 ]:
磺草灵
[ 英文名 ]:
Asulam
[中文别名 ]:
[英文别名 ]:
- methyl N-(4-aminobenzenesulfonyl)carbamate
- Jonnix
- Methyl sulphanilylcarbamate
- Asulox
- Plakin
- methyl N-(4-aminophenyl)sulfonylcarbamate
- Methyl N-(4-aminophenylsulfonyl)carbamate
- MFCD00055534
- N-(methoxycarbonyl)-4-(amino)benzenesulfonamide
- ASULAM
磺草灵物理化学性质
[ 密度 ]:
1.418g/cm3
[ 熔点 ]:
142-144ºC (dec.)
[ 分子式 ]:
C8H10N2O4S
[ 分子量 ]:
230.24100
[ 精确质量 ]:
230.03600
[ PSA ]:
106.87000
[ LogP ]:
2.36640
[ 折射率 ]:
1.5690 (estimate)
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
磺草灵MSDS
磺草灵毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- FD1190000
- CHEMICAL NAME :
- Carbamic acid, sulfanilyl-, methyl ester
- CAS REGISTRY NUMBER :
- 3337-71-1
- BEILSTEIN REFERENCE NO. :
- 2697523
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 17
- MOLECULAR FORMULA :
- C8-H10-N2-O4-S
- MOLECULAR WEIGHT :
- 230.26
- WISWESSER LINE NOTATION :
- WSQR DMMVO1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 2,90,1977
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >18900 mg/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >10 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,204,1971
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A021,1983
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - pigeon
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,39,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - chicken
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,39,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - quail
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,39,1991 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 273 gm/kg/13W-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Kidney, Ureter, Bladder - interstitial nephritis Nutritional and Gross Metabolic - weight loss or decreased weight gain
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 219 gm/kg/2Y-C
- TOXIC EFFECTS :
- Endocrine - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 273 gm/kg/26W-C
- TOXIC EFFECTS :
- Endocrine - hyperglycemia Endocrine - changes in thyroid weight Blood - changes in other cell count (unspecified)
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 110 gm/kg/2Y-C
- TOXIC EFFECTS :
- Nutritional and Gross Metabolic - weight loss or decreased weight gain
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990 ** REPRODUCTIVE DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 24 gm/kg
- SEX/DURATION :
- female 5-20 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Maternal Effects - other effects
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 15,497,1990 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989
磺草灵安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn: Harmful;
[ 风险声明 (欧洲) ]:
R22
[ 危险品运输编码 ]:
NONH for all modes of transport
[ RTECS号 ]:
FD1190000
[ 海关编码 ]:
2935009016
磺草灵合成路线
磺草灵上下游产品
磺草灵上游产品
磺草灵下游产品
磺草灵制备
（1）4-氨基苯磺酰胺与氯代甲酸甲酯反应，该反应在水或有机溶剂中进行，缚碱剂存在下，在水介质中的最适宜反应温度为10～20℃，在有机介质中于回流温度下，前者用氢氧化钠，后者在丙酮中用碳酸钾，即制得磺草灵。
（2）14kg(10.0mol)4-乙酰氨基苯磺酰胺、1.75kg(12.7mol)无水碳酸钾和16L丙酮的混合物在搅拌下，缓慢加入1.14kg(12.1mol)氯甲酸甲酯。加毕，混合物搅拌下回流18小时，然后冷却制室温，过滤，固体部分悬浮水中，用盐酸酸化，得中间物粗品，然后溶解在1mol碳酸氢钠水溶液中，过滤后的绿叶再用盐酸酸化至酸性，精制的中间物乙酰氨基苯磺酰氨基甲酸甲酯，收率45.9%，产量1.25kg，白色固体，熔点235～237℃。将572g(2.1mol)中间物溶解在2mol氢氧化钠中，室温下放置2天后，用浓盐酸酸化，生成的沉淀物用2mol/L盐酸提取，起先得到的提取盐酸加到滤液中，然后用50%情；氢氧化钠水溶液调PH值至4，得289g(1.25mol)磺草灵，收率60%，熔点145～146℃。用盐酸提取子不溶物（218g,0.8mol）加水分解的残留物为中间物，可循环使用，水解收率达96%。
3.由氯甲酸甲酯与甲醇回流反应，脱去１分子氯化氢，生成碳酸二甲酯；然后将碳酸二甲酯在甲醇钠存在下与对氨基苯磺酰胺作用，生成磺草灵。
磺草灵海关
[ 海关编码 ]: 2935009016
[ 中文概述 ]:
2935009016 氟磺胺草醚,磺草灵,吲唑磺菌胺等〔包括单嘧磺酯,磺草唑胺,三氟啶磺隆钠〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:35.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ 监管条件 ]: S.进出口农药登记证明
[ Summary ]:
2935009016 methyl (4-aminophenyl)sulfonylcarbamate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:35.0%
磺草灵文献
J. Phys. Chem. A 117(10) , 2125-37, (2013)
The photophysics of the neutral molecular form of the herbicide asulam has been described in a joint experimental and theoretical, at the CASPT2 level, study. The unique π → π* aromatic electronic tra...
Soil photolysis of herbicides in a moisture- and temperature-controlled environment.J. Agric. Food Chem. 51(15) , 4331-7, (2003)
The problem of maintaining the moisture content of samples throughout the course of a soil photolysis study is addressed. The photolytic degradations of asulam, triclopyr, acifluorfen, and atrazine we...
Effects of asulam on some microbial activities of three soils.Bull. Environ. Contam. Toxicol. 25(1) , 15-22, (1980)
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥188.0/250mg
联系人：刘佳
产品详情：黄草灵
公司名：上海源溪生物科技有限公司
区域：上海市浦东新区
价格：
￥需询单/1g
联系人：赖经理
产品详情：Asulam
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥288.9/1ml
￥175.9/1ml
￥278.9/250mg
￥需询单/1g
联系人：阿拉丁李高志
产品详情：黄草灵
公司名：广东翁江化学试剂有限公司
区域：韶关市翁源县
价格：
￥6400.0/500g
￥320.0/250mg
联系人：朱丽丹
产品详情：黄草灵
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相关化合物
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