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双(2-乙基己基)磷酸

双(2-乙基己基)磷酸名称

[ CAS 号 ]:
3658-48-8

[ 中文名 ]:
双(2-乙基己基)亚磷酸酯

[ 英文名 ]:
UNII:J9H3L1N82V

[中文别名 ]:

二(2-乙基己基)亚磷酸

[英文别名 ]:

Bis(2-ethylhexyl) phosphonate
bis(2-ethylhexyl)phosphite
MFCD00009490
diisooctylphosphite
Phosphonic acid, bis(2-ethylhexyl) ester
DIOCTYL PHOSPHITE
di-2-ethylhexyl hydrogen phosphate
Bis(2-ethylhexyl)phosphonat
DIOCTYL HYDROGEN PHOSPHITE
Syn-O-Ad P-310

双(2-乙基己基)磷酸物理化学性质

[ 密度 ]:
0.916 g/mL at 25 °C(lit.)

[ 沸点 ]:
372.9±11.0 °C at 760 mmHg

[ 分子式 ]:
C₁₆H₃₅O₃P

[ 分子量 ]:
306.421

[ 闪点 ]:
198.8±13.5 °C

[ 精确质量 ]:
306.232391

[ PSA ]:
59.00000

[ LogP ]:
5.76

[ 外观性状 ]:
淡黄色液体

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
n20/D 1.442(lit.)

[ 储存条件 ]:
室温

双(2-乙基己基)磷酸MSDS

双(2-乙基己基)磷酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SZ6840000

CHEMICAL NAME :: Phosphonic acid, bis(2-ethylhexyl) ester

CAS REGISTRY NUMBER :: 3658-48-8

BEILSTEIN REFERENCE NO. :: 1711893

LAST UPDATED :: 199712

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C16-H35-O3-P

MOLECULAR WEIGHT :: 306.48

WISWESSER LINE NOTATION :: 4Y2&1OPHO&O1Y4&2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 18,464,1958 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 11900 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ALBRW* Albright & Wilson Inc. (P.O. Box 26229, Richmond, VA 23260-6229) Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >20 gm/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ALBRW* Albright & Wilson Inc. (P.O. Box 26229, Richmond, VA 23260-6229) Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1500 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

REFERENCE :: AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 18,464,1958

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 620 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

REFERENCE :: AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 18,464,1958

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 4500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ALBRW* Albright & Wilson Inc. (P.O. Box 26229, Richmond, VA 23260-6229) Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - acute pulmonary edema Lungs, Thorax, or Respiration - other changes

REFERENCE :: AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 18,464,1958

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 700 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

REFERENCE :: AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 18,464,1958 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1156 No. of Facilities: 1888 (estimated) No. of Industries: 16 No. of Occupations: 17 No. of Employees: 13678 (estimated) No. of Female Employees: 80 (estimated)

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双(2-乙基己基)磷酸安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
SZ6840000

[ 海关编码 ]:
2920909090

双(2-乙基己基)磷酸合成路线

双(2-乙基己基)磷酸上下游产品

双(2-乙基己基)磷酸上游产品

双(2-乙基己基)磷酸下游产品

双(2-乙基己基)磷酸海关

[ 海关编码 ]: 2920909090

[ 中文概述 ]:
2920909090 其他无机酸酯（不包括卤化氢的酯）（包括其盐及它们的卤化，磺化，硝化和亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

双(2-乙基己基)磷酸文献

Reactions of Chemical Warfare Agent Simulants in the Common Ion Binary Ionic Liquid 1, 2-Dimethyl-3-propylimidazolium/Copper (II) Bis (trifluoromethylsulfonyl) amide. Wilkes JS, et al.

Ind. Eng. Chem. Res. 48(13) , 6203-11, (2009)

Kinetics and mechanism of the interfacial mass transfer of europium (3+) and americium (3+) in the system bis (2-ethylhexyl) phosphate-n-dodecane-sodium chloride-hydrochloric acid-water. Danesi PR and Vandegrift GF.

J. Phys. Chem. 85(24) , 3646-51, (1981)

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