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6,6′-二甲基-2,2′-联吡啶

6,6′-二甲基-2,2′-联吡啶名称

[ CAS 号 ]:
4411-80-7

[ 中文名 ]:
6,6′-二甲基-2,2′-联吡啶

[ 英文名 ]:
6,6'-Dimethyl-2,2'-bipyridine

[中文别名 ]:

[英文别名 ]:

2-methyl-6-(6-methylpyridin-2-yl)pyridine
MFCD00059776
6,6'-DiMethyl-2,2'-bipyridyl
6,6'-Dimethyl-2,2'-bipyridine
6,6′-Dimethyl-2,2′-dipyridyl
6,6'-Di-2-picolyl
6,6'-Bi-2-picoline
EINECS 224-566-5
6,6'-Dimethyl-2,2'-dipyridyl

6,6′-二甲基-2,2′-联吡啶物理化学性质

[ 密度 ]:
1.06g/cm3

[ 沸点 ]:
286 °C

[ 熔点 ]:
93-95 °C(lit.)

[ 分子式 ]:
C₁₂H₁₂N₂

[ 分子量 ]:
184.23700

[ 闪点 ]:
104.9ºC

[ 精确质量 ]:
184.10000

[ PSA ]:
25.78000

[ LogP ]:
2.76040

[ 外观性状 ]:
固体

[ 折射率 ]:
1.566

[ 储存条件 ]:
室温

6,6′-二甲基-2,2′-联吡啶MSDS

详细MSDS(安全技术说明书)

6,6′-二甲基-2,2′-联吡啶毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DW1767000

CHEMICAL NAME :: 2,2'-Bipyridine, 6,6'-dimethyl-

CAS REGISTRY NUMBER :: 4411-80-7

BEILSTEIN REFERENCE NO. :: 0128972

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C12-H12-N2

MOLECULAR WEIGHT :: 184.26

WISWESSER LINE NOTATION :: T6NJ F1 B- BT6NJ F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 190 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TOXIA6 Toxicon. (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW, UK) V.1- 1962- Volume(issue)/page/year: 23,815,1985

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6,6′-二甲基-2,2′-联吡啶安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
26-36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
DW1767000

[ 海关编码 ]:
2933399090

6,6′-二甲基-2,2′-联吡啶合成路线

详细合成路线

6,6′-二甲基-2,2′-联吡啶上下游产品

6,6′-二甲基-2,2′-联吡啶上游产品

6,6′-二甲基-2,2′-联吡啶下游产品

6,6′-二甲基-2,2′-联吡啶海关

[ 海关编码 ]: 2933399090

[ 中文概述 ]:
2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

6,6′-二甲基-2,2′-联吡啶文献

Complexes of Pd(II), Pt(II), Cu(II), Co(II) and Zn(II) chlorides with 6,6'-dimethyl-2,2'-dipyridyl. Newkome GR, et al.

J. Inorg. Nucl. Chem. 43(7) , 1529-1531, (1981)

6,6'-Dimethyl-2,2'-bipyridyl. Sengül A, et al.

Acta Crystallogr. C Struct. Chem. 54(5) , 661-662, (1998)

Two convenient and high-yielding preparations of 6, 6'-dimethyl-2, 2'-bipyridine by homocoupling of 6-bromopicoline. Cassol TM, et al.

Tetrahedron Lett. 41(43) , 8203-8206, (2000)

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