1,1'-二叔丁基二磷烷
1,1'-二叔丁基二磷烷名称
[ CAS 号 ]:
470480-32-1
[ 中文名 ]:
1,1'-二叔丁基二磷烷
[ 英文名 ]:
(S,S',R,R')-Tangphos
[中文别名 ]:
[英文别名 ]:
- (S,S',R,R')-Tangphos
- 1S,1S',2R,2R'-1,1'-di-t-butyl-[2,2']diphospholane
- MFCD06658118
1,1'-二叔丁基二磷烷物理化学性质
[ 沸点 ]:
353.584ºC at 760 mmHg
[ 熔点 ]:
60-65ºC
[ 分子式 ]:
C16H32P2
[ 分子量 ]:
286.37300
[ 闪点 ]:
176.043ºC
[ 精确质量 ]:
286.19800
[ PSA ]:
27.18000
[ LogP ]:
5.87200
1,1'-二叔丁基二磷烷MSDS
1,1'-二叔丁基二磷烷安全信息
[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ 风险声明 (欧洲) ]:
36/37/38
[ 安全声明 (欧洲) ]:
22-24/25
[ WGK德国 ]:
3
1,1'-二叔丁基二磷烷合成路线
1,1'-二叔丁基二磷烷文献
Org. Lett. 4 , 4159, (2002)
The Rh-TangPhos complex is an efficient hydrogenation catalyst for making chiral beta-amino acid derivatives. With the Rh-TangPhos system, high enantioselectivities (up to 99.6%) and turnover numbers ...
Asymmetric hydrogenation of itaconic acid and enol acetate derivatives with the Rh-TangPhos catalyst.Org. Lett. 5 , 205, (2003)
[reaction: see text] The Rh-TangPhos catalyst has been used for asymmetric hydrogenation of itaconic acid and enol acetate derivatives. A variety of chiral 2-substituted succinic acids and chiral acet...
A chiral 1,2-bisphospholane ligand with a novel structural motif: applications in highly enantioselective Rh-catalyzed hydrogenations.Angew. Chem. Int. Ed. Engl. 41 , 1612, (2002)
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相关化合物
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