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苯丙炔酸甲酯

苯丙炔酸甲酯名称

[ CAS 号 ]:
4891-38-7

[ 中文名 ]:
苯丙炔酸甲酯

[ 英文名 ]:
Methyl 3-phenyl-2-propynoate

[中文别名 ]:

苯基丙炔酸甲酯

[英文别名 ]:

Phenylpropynoic acid methyl ester
Methyl Phenylpropiolate
Propiolic acid, 3-phenyl-, methyl ester
methyl 3-phenylprop-2-ynoate
Phenylpropargylic Acid Methyl Ester
2-Propynoic acid, 3-phenyl-, methyl ester
Methyl 3-phenyl-2-propynoate
MFCD00041685
Phenylpropiolic Acid Methyl Ester

苯丙炔酸甲酯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
247.9±9.0 °C at 760 mmHg

[ 熔点 ]:
26ºC

[ 分子式 ]:
C₁₀H₈O₂

[ 分子量 ]:
160.169

[ 闪点 ]:
117.4±6.7 °C

[ 精确质量 ]:
160.052429

[ PSA ]:
26.30000

[ LogP ]:
3.19

[ 外观性状 ]:
透明无色至淡黄色液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.546

[ 储存条件 ]:
室温

苯丙炔酸甲酯MSDS

详细MSDS(安全技术说明书)

苯丙炔酸甲酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319

[ 警示性声明 ]:
P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/38

[ 安全声明 (欧洲) ]:
26-36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2916399090

苯丙炔酸甲酯上下游产品

苯丙炔酸甲酯上游产品

苯丙炔酸甲酯下游产品

苯丙炔酸甲酯海关

[ 海关编码 ]: 2916399090

[ 中文概述 ]:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

苯丙炔酸甲酯文献

Regio- and enantioselective intermolecular rhodium-catalyzed [2+2+2] carbocyclization reactions of 1,6-enynes with methyl arylpropiolates.

J. Am. Chem. Soc. 127(36) , 12466-7, (2005)

Transition metal-catalyzed [m+n+o] carbocyclization reactions provide powerful methods for the construction of complex polycyclic systems that are generally not accessible through classical pericyclic...

Steric effects on reactivity in silicon chemistry. Cartledge FK.

Organometallics 2(3) , 425-430, (1983)

Preparation and Structures of Methyl Phenylpropiolate-Iron Carbonyl Complexes. A New Dicarbonyl-p-cyclopentadienyloxy-s-vinyliron Compound. Dahl LF, et al.

J. Am. Chem. Soc. 88(3) , 446-452, (1966)

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