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氮杂环丁烷

氮杂环丁烷用途

有机合成。

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氮杂环丁烷名称

[ CAS 号 ]:
503-29-7

[ 中文名 ]:
杂氮环丁烷

[ 英文名 ]:
Azetidine

[中文别名 ]:

[英文别名 ]:

Azetidine
MFCD00005165
Trimethylenimine
EINECS 207-963-8
1,3-Propylenimine
Azetidin
trimethyleneimine
Azacyclobutane
UNII-37S883XDWR

氮杂环丁烷物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
64.9±8.0 °C at 760 mmHg

[ 分子式 ]:
C₃H₇N

[ 分子量 ]:
57.094

[ 闪点 ]:
-23.6±16.5 °C

[ 精确质量 ]:
57.057850

[ PSA ]:
12.03000

[ LogP ]:
-0.20

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
161.5±0.1 mmHg at 25°C

[ 折射率 ]:
1.426

[ 储存条件 ]:
2-8°C

[ 水溶解性 ]:
miscible

氮杂环丁烷MSDS

氮杂环丁烷安全信息

[ 符号 ]:

GHS02, GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H314

[ 警示性声明 ]:
P210-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
F: Flammable;C: Corrosive;

[ 风险声明 (欧洲) ]:
R11;R34

[ 安全声明 (欧洲) ]:
S16-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2733 3/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
I

[ 危险类别 ]:
3.1

[ 海关编码 ]:
29339990

氮杂环丁烷合成路线

氮杂环丁烷上下游产品

氮杂环丁烷上游产品

氮杂环丁烷下游产品

氮杂环丁烷海关

[ 海关编码 ]: 2933990090

[ 中文概述 ]:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

氮杂环丁烷文献

Synthesis from D-altrose of (5R,6R,7R,8S)-5,7-dihydroxy-8-hydroxymethylconidine and 2,4-dideoxy-2,4-imino-D-glucitol, azetidine analogues of swainsonine and 1,4-dideoxy-1,4-imino-D-mannitol.

Org. Lett. 14(16) , 4174-7, (2012)

Ring closure of a 3,5-di-O-triflate derived from D-altrose with benzylamine allowed the formation of both monocyclic and bicyclic azetidine analogues of swainsonine.

Identification of spirocyclic piperidine-azetidine inverse agonists of the ghrelin receptor.

Bioorg. Med. Chem. Lett. 22(13) , 4281-7, (2012)

The discovery of spirocyclic piperidine-azetidine inverse agonists of the ghrelin receptor is described. The characterization and redressing of the issues associated with these compounds is detailed. ...

Complex N-heterocycle synthesis via iron-catalyzed, direct C-H bond amination.

Science 340(6132) , 591-5, (2013)

The manipulation of traditionally unreactive functional groups is of paramount importance in modern chemical synthesis. We have developed an iron-dipyrrinato catalyst that leverages the reactivity of ...

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