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禾草灵

禾草灵用途

Diclofop-methyl 是一种常见的生后除草剂,广泛应用于农业生产。Diclofop-methyl 提高离体燕麦根液泡膜的质子通透性。
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禾草灵名称

[ CAS 号 ]:
51338-27-3

[ 中文名 ]:
禾草灵

[ 英文名 ]:
DICLOFOP-METHYL

[中文别名 ]:

[英文别名 ]:

禾草灵生物活性

[ 描述 ]:

Diclofop-methyl 是一种常见的生后除草剂,广泛应用于农业生产。Diclofop-methyl 提高离体燕麦根液泡膜的质子通透性。

[ 相关类别 ]:

研究领域 >> 其他
信号通路 >> 其他 >> 其他

[体外研究]

甲基双氯磷(1微摩尔)显著降低了ATP存在下产生的稳态H(+)梯度[1]。

[参考文献]

[1]. Ratterman DM, et al. Diclofop-methyl increases the proton permeability of isolated oat-root tonoplast. Plant Physiol. 1989;91(2):756-765.

[2]. Li X, et al. The interactive effects of diclofop-methyl and silver nanoparticles on Arabidopsis thaliana: Growth, photosynthesis and antioxidant system. Environ Pollut. 2018;232:212-219.

禾草灵物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
408.0±45.0 °C at 760 mmHg

[ 熔点 ]:
39-41°C

[ 分子式 ]:
C16H14Cl2O4

[ 分子量 ]:
341.186

[ 闪点 ]:
150.3±27.7 °C

[ 精确质量 ]:
340.026917

[ PSA ]:
44.76000

[ LogP ]:
4.24

[ 外观性状 ]:
暗棕色液体无明显杂质

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.562

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

[ 水溶解性 ]:
0.005 g/100 mL

禾草灵MSDS

禾草灵毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UF1180000
CHEMICAL NAME :
Propionic acid, 2-(4-(2,4-dichlorophenoxy)phenoxy)-, methyl ester
CAS REGISTRY NUMBER :
51338-27-3
LAST UPDATED :
199612
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C16-H14-Cl2-O4
MOLECULAR WEIGHT :
341.20
WISWESSER LINE NOTATION :
GR CG DOR DOY1&VO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
512 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C165,1991
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8300 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
586 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZDBEA9 Zdravookhranenie Belorussii. Public Health Service of White Russia. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1955- Volume(issue)/page/year: (3),29,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,262,1991 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
672 mg/kg/4W-C
TOXIC EFFECTS :
Liver - changes in liver weight Blood - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.)
REFERENCE :
BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 40,153,1988 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989
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禾草灵安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H317-H410

[ 警示性声明 ]:
P273-P280-P501

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R22;R43;R50/53

[ 安全声明 (欧洲) ]:
S24-S37-S60-S61

[ 危险品运输编码 ]:
UN 3077

[ RTECS号 ]:
UF1180000

[ 海关编码 ]:
2918990025

禾草灵合成路线

禾草灵上下游产品

禾草灵海关

[ 海关编码 ]: 2918990090

[ 中文概述 ]:
2918990090. 其他含其他附加含氧基羧酸(包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

禾草灵文献

Characterisation of target-site resistance to ACCase-inhibiting herbicides in the weed Alopecurus myosuroides (black-grass).

Pest Manag. Sci. 59(2) , 190-201, (2003)

Resistance to aryloxyphenoxypropionate (AOPP), cyclohexanedione (CHD) and phenylurea herbicides was determined in UK populations of Alopecurus myosuroides Huds. Two populations (Oxford AA1, Notts. A1)...

Genetic control of a cytochrome P450 metabolism-based herbicide resistance mechanism in Lolium rigidum.

Heredity (Edinb.) 106(5) , 817-24, (2011)

The dynamics of herbicide resistance evolution in plants are influenced by many factors, especially the biochemical and genetic basis of resistance. Herbicide resistance can be endowed by enhanced rat...

Recurrent selection with reduced herbicide rates results in the rapid evolution of herbicide resistance in Lolium rigidum.

Theor. Appl. Genet. 110(6) , 1154-66, (2005)

There has been much debate regarding the potential for reduced rates of herbicide application to accelerate evolution of herbicide resistance. We report a series of experiments that demonstrate the po...


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推荐生产厂家/供应商:

公司名:上海化源生化科技有限公司

区域:上海市普陀区

价格:

联系人:徐经理

产品详情:禾草灵


公司名:上海吉至生化科技有限公司

区域:上海市奉贤区

价格:
¥798.0/250mg

联系人:刘佳

产品详情:禾草灵


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