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1,4-萘二酚

1,4-萘二酚名称

[ CAS 号 ]:
571-60-8

[ 中文名 ]:
1,4-二羟基萘

[ 英文名 ]:
BENZOHYDROQUINONE

[中文别名 ]:

[英文别名 ]:

BENZOHYDROQUINONE
1,4-Naphthalenediol
EINECS 209-336-4
MFCD00003977
1,4-Dihydroxynaphthalene
Naphthalene-1,4-diol

1,4-萘二酚物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
391.0±15.0 °C at 760 mmHg

[ 熔点 ]:
191-192 °C (dec.)

[ 分子式 ]:
C₁₀H₈O₂

[ 分子量 ]:
160.169

[ 闪点 ]:
202.5±15.0 °C

[ 精确质量 ]:
160.052429

[ PSA ]:
40.46000

[ LogP ]:
1.88

[ 外观性状 ]:
近乎于白色固体

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.726

[ 储存条件 ]:
室温，密封，干燥，避光，惰性气体

[ 水溶解性 ]:
slightly soluble

1,4-萘二酚MSDS

1,4-萘二酚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QJ4730000

CHEMICAL NAME :: 1,4-Naphthalenediol

CAS REGISTRY NUMBER :: 571-60-8

BEILSTEIN REFERENCE NO. :: 1307689

LAST UPDATED :: 199709

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C10-H8-O2

MOLECULAR WEIGHT :: 160.18

WISWESSER LINE NOTATION :: L66J BQ EQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 5 nmol/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 371,293,1996 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X3916 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 56 (estimated) No. of Female Employees: 35 (estimated)

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1,4-萘二酚安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H315-H318-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R25;R36/37/38;R43

[ 安全声明 (欧洲) ]:
S26-S39-S45-S36/37/39-S28A-S24

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
QJ4730000

[ 海关编码 ]:
2907299090

1,4-萘二酚合成路线

1,4-萘二酚海关

[ 海关编码 ]: 2907299090

[ 中文概述 ]:
2907299090 其他多元酚，酚醇。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2907299090 polyphenols; phenol-alcohols。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:5.5%。general tariff:30.0%

1,4-萘二酚文献

2,3-Disubstituted-1,4-naphthoquinones, 12H-benzo[b]phenothiazine-6,11-diones and related compounds: synthesis and biological evaluation as potential antiproliferative and antifungal agents.

Eur. J. Med. Chem. 44 , 1086-92, (2009)

A series of 2-chloro-3-arylsulfanyl-[1,4]naphthoquinones (2), 2,3-bis-arylsulfanyl-[1,4]naphthoquinones (3) and 12H-benzo[b]phenothiazine-6,11-diones and their analogs 6-8 were synthesized and evaluat...

A laccase-catalysed one-pot synthesis of aminonaphthoquinones and their anticancer activity

Bioorg. Med. Chem. 20(14) , 4472-81, (2012)

Nuclear monoamination of a 1,4-naphthohydroquinone with primary aromatic amines was catalysed by the commercial laccase, Novozym 51003, from Novozymes to afford aminonaphthoquinones. The synthesis was...

Dual effects of superoxide dismutase on the autoxidation of 1,4-naphthohydroquinone.

Free Radic. Biol. Med. 8(1) , 21-4, (1990)

The autoxidation of 1,4-naphthohydroquinone, in a phosphate, EDTA buffer at pH 7.4, exhibits an autocatalysis whose lag phase becomes more pronounced in the presence of either the Cu,Zn- or the Mn-con...

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