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叔丁氧基双(二甲胺基)甲烷

叔丁氧基双(二甲胺基)甲烷用途

-20℃，密闭冷藏

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叔丁氧基双(二甲胺基)甲烷名称

[ CAS 号 ]:
5815-08-7

[ 中文名 ]:
叔丁氧基二(二甲基氨基)甲烷

[ 英文名 ]:
tert-Butoxy bis(dimethylamino)methane

[中文别名 ]:

[英文别名 ]:

Bredereck’s reagent
tert-Butoxy bis(dimethylamino)methane
EINECS 227-383-9
tert-butoxybis(dimethylamino)methane
Brederick’s reagent
MFCD00042858
1-tert-Butoxy-N,N,N',N'-tetramethylmethanediamine
EINECS 227-383-9

叔丁氧基双(二甲胺基)甲烷物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
176.9±20.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₂₂N₂O

[ 分子量 ]:
174.284

[ 闪点 ]:
35.2±19.0 °C

[ 精确质量 ]:
174.173218

[ PSA ]:
15.71000

[ LogP ]:
2.14

[ 外观性状 ]:
无色到浅黄色液体

[ 蒸汽压 ]:
1.1±0.3 mmHg at 25°C

[ 折射率 ]:
1.446

[ 储存条件 ]:
Freezer (-20°C)

叔丁氧基双(二甲胺基)甲烷MSDS

叔丁氧基双(二甲胺基)甲烷安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R10;R36/37/38

[ 安全声明 (欧洲) ]:
S26

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2922199090

叔丁氧基双(二甲胺基)甲烷合成路线

叔丁氧基双(二甲胺基)甲烷上下游产品

叔丁氧基双(二甲胺基)甲烷上游产品

叔丁氧基双(二甲胺基)甲烷下游产品

叔丁氧基双(二甲胺基)甲烷海关

[ 海关编码 ]: 2922199090

[ 中文概述 ]:
2922199090. 其他氨基醇及其醚，酯和它们的盐（但含一种以上含氧基的除外）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

叔丁氧基双(二甲胺基)甲烷文献

Specific CLK inhibitors from a novel chemotype for regulation of alternative splicing.

Chem. Biol. 18 , 67-76, (2011)

There is a growing recognition of the importance of protein kinases in the control of alternative splicing. To define the underlying regulatory mechanisms, highly selective inhibitors are needed. Here...

Macrocyclization by nickel-catalyzed, ester-promoted, epoxide-alkyne reductive coupling: total synthesis of (-)-gloeosporone.

Angew. Chem. Int. Ed. Engl. 48(29) , 5366-8, (2009)

Ringing the changes: The total synthesis of the title compound centers around a novel strategy that employs a nickel(0)-phosphine complex and triethyl borane in an efficient closure of a 14-membered r...

First total synthesis of the 2,7-naphthyridine alkaloids lophocladine a and B.

Arch. Pharm. (Weinheim) 339(12) , 677-9, (2006)

The one-pot reaction of 4-benzylpyridine-3-carbonitrile with Bredereck's reagent and subsequent treatment with either glacial acetic acid and sulfuric acid or ammonium acetate provided the new bioacti...

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