叔丁氧基双(二甲胺基)甲烷
叔丁氧基双(二甲胺基)甲烷结构式
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常用名 | 叔丁氧基双(二甲胺基)甲烷 | 英文名 | tert-Butoxy bis(dimethylamino)methane |
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| CAS号 | 5815-08-7 | 分子量 | 174.284 | |
| 密度 | 0.9±0.1 g/cm3 | 沸点 | 176.9±20.0 °C at 760 mmHg | |
| 分子式 | C9H22N2O | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 35.2±19.0 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Warning |
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Specific CLK inhibitors from a novel chemotype for regulation of alternative splicing.
Chem. Biol. 18 , 67-76, (2011) There is a growing recognition of the importance of protein kinases in the control of alternative splicing. To define the underlying regulatory mechanisms, highly selective inhibitors are needed. Here, we report the discovery and characterization of the dichl... |
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Macrocyclization by nickel-catalyzed, ester-promoted, epoxide-alkyne reductive coupling: total synthesis of (-)-gloeosporone.
Angew. Chem. Int. Ed. Engl. 48(29) , 5366-8, (2009) Ringing the changes: The total synthesis of the title compound centers around a novel strategy that employs a nickel(0)-phosphine complex and triethyl borane in an efficient closure of a 14-membered ring through C--C bond formation (see scheme; cod=cyclooctad... |
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First total synthesis of the 2,7-naphthyridine alkaloids lophocladine a and B.
Arch. Pharm. (Weinheim) 339(12) , 677-9, (2006) The one-pot reaction of 4-benzylpyridine-3-carbonitrile with Bredereck's reagent and subsequent treatment with either glacial acetic acid and sulfuric acid or ammonium acetate provided the new bioactive naphthyridine alkaloids lophocladine A and B, respective... |
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R.F. Abdulla, R.S. Brinkmeyer
Tetrahedron 35 , 1675, (1979)
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W. Haefliger, H. Knecht
Tetrahedron Lett. 25 , 285, (1984)
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