一甲胺盐酸盐
一甲胺盐酸盐用途
用作分析试剂,也用于有机合成
【用途二】
分析试剂,有机合成。
一甲胺盐酸盐名称
[ CAS 号 ]:
593-51-1
[ 中文名 ]:
盐酸甲胺
[ 英文名 ]:
Methylamine hydrochloride
[中文别名 ]:
[英文别名 ]:
- methanamine hydrochloride
- Methyl-ammonium
- metylamine hydrochloride
- Methanamine, hydrochloride (1:1)
- METHYLAMINE HCL
- MONOMETHYLAMINE HCL
- methylammonium chloride
- Methanaminium chloride
- Methylamine hydrochl
- Methaniminium
一甲胺盐酸盐物理化学性质
[ 沸点 ]:
225-230 °C15 mm Hg(lit.)
[ 熔点 ]:
231-233 °C(lit.)
[ 分子式 ]:
CH6ClN
[ 分子量 ]:
67.518
[ 闪点 ]:
225-230°C/15mm
[ 精确质量 ]:
67.018875
[ PSA ]:
26.02000
[ LogP ]:
1.07720
[ 外观性状 ]:
白色至淡黄褐色的固体
[ 储存条件 ]:
库房低温,通风,干燥,防火,与氧化剂,强酸分开存放
[ 稳定性 ]:
Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents.
[ 水溶解性 ]:
soluble
一甲胺盐酸盐MSDS
一甲胺盐酸盐毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- PA0603000
- CHEMICAL NAME :
- Methanamine, hydrochloride
- CAS REGISTRY NUMBER :
- 593-51-1
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 7
- MOLECULAR FORMULA :
- C-H5-N.Cl-H
- MOLECULAR WEIGHT :
- 67.53
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1600 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- INHTE5 Inhalation Toxicology. (Hemisphere Publishing Corp., c/o Taylor & Francis Inc., 1900 Frost Rd., Suite 101, Bristol, PA 19007) V.1- 1989- Volume(issue)/page/year: 2,29,1990
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 2160 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- YKKZAJ Yakugaku Zasshi. Journal of Pharmacy. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) No.1- 1881- Volume(issue)/page/year: 97,1117,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 610 mg/kg/5D-I
- TOXIC EFFECTS :
- Blood - changes in leukocyte (WBC) count
- REFERENCE :
- JTEHD6 Journal of Toxicology and Environmental Health. (Hemisphere Pub., 1025 Vermont Ave., NW, Washington, DC 20005) V.1- 1975/76- Volume(issue)/page/year: 47,479,1996 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4270 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 28 (estimated)
一甲胺盐酸盐安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302-H315-H319-H335
[ 警示性声明 ]:
P261-P305 + P351 + P338
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful
[ 风险声明 (欧洲) ]:
R22;R36/37/38
[ 安全声明 (欧洲) ]:
S26-S37/39
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
1
[ RTECS号 ]:
PA0603000
[ 海关编码 ]:
29211190
一甲胺盐酸盐合成路线
一甲胺盐酸盐上下游产品
一甲胺盐酸盐上游产品
一甲胺盐酸盐下游产品
一甲胺盐酸盐制备
1.甲胺溶液在冷却下加入化学纯盐酸,调至ph=2~3,然后脱色过滤、减压浓缩后,再调ph=2~3,冷却滤出结晶,即为成品。
反应式为:
一甲胺盐酸盐海关
[ 海关编码 ]: 2921110090
[ 中文概述 ]:
2921110090 甲胺,三甲胺及其盐。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单
[ 检验检疫 ]: M.进口商品检验 N.出口商品检验
[ Summary ]:
HS: 2921110090. methylamine, di- or trimethylamine and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:ab(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. general tariff:30.0%
一甲胺盐酸盐文献
J. Am. Soc. Mass Spectrom. 25(10) , 1747-54, (2014)
Information on the higher-order structure is important in the development of biopharmaceutical drugs. Recently, hydrogen/deuterium exchange coupled with mass spectrometry (HDX-MS) has been widely used...
Methylamine utilization via the N-methylglutamate pathway in Methylobacterium extorquens PA1 involves a novel flow of carbon through C1 assimilation and dissimilation pathways.J. Bacteriol. 196(23) , 4130-9, (2014)
Methylotrophs grow on reduced single-carbon compounds like methylamine as the sole source of carbon and energy. In Methylobacterium extorquens AM1, the best-studied aerobic methylotroph, a periplasmic...
Quantitative liquid chromatography-electrospray ionization-mass spectrometry analysis of amine-containing metabolites derivatized with cyanuric chloride and methylamine isotopologues.J. Chromatogr. A. 1388 , 60-8, (2015)
Electrospray ionization (ESI) is the most useful interface for mass spectrometry associated with liquid chromatography (LC). However, analyses of polar metabolites become a challenge because the high ...
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