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三甲基磷

三甲基磷用途

2、用途

是制备有机磷化合物的中新时代本及常用的含膦配体。

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三甲基磷名称

[ CAS 号 ]:
594-09-2

[ 中文名 ]:
三甲基膦

[ 英文名 ]:
Trimethylphosphine

[中文别名 ]:

三甲基磷

[英文别名 ]:

Phosphine, trimethyl-
Trimethylphosphine
TRIMETHYLPHOSPHORUS
EINECS 209-823-1
MFCD00008510
trimethylphosphane

三甲基磷物理化学性质

[ 密度 ]:
0.872 g/mL at 25 °C

[ 沸点 ]:
40.5±9.0 °C at 760 mmHg

[ 熔点 ]:
−86 °C(lit.)

[ 分子式 ]:
C₃H₉P

[ 分子量 ]:
76.077

[ 闪点 ]:
-30.0±0.0 °C

[ 精确质量 ]:
76.044189

[ PSA ]:
13.59000

[ LogP ]:
0.82

[ 外观性状 ]:
无色液体带有一种强烈的,令人不愉快的气味

[ 蒸汽压 ]:
433.8±0.1 mmHg at 25°C

[ 折射率 ]:
n20/D 1.428(lit.)

[ 储存条件 ]:
2-8°C

三甲基磷MSDS

三甲基磷安全信息

[ 符号 ]:

GHS02, GHS07, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302-H315-H319-H335-H351

[ 补充危害声明 ]:
May form explosive peroxides.

[ 警示性声明 ]:
P210-P280-P301 + P312 + P330-P305 + P351 + P338-P370 + P378-P403 + P235

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;Xi:Irritant;

[ 风险声明 (欧洲) ]:
R11;R36/37/38

[ 安全声明 (欧洲) ]:
S9-S16-S26-S36/37/39-S62-S36/37-S7/9-S33

[ 危险品运输编码 ]:
UN 1993 3/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
I

[ 危险类别 ]:
4.2

三甲基磷合成路线

三甲基磷上下游产品

三甲基磷上游产品

三甲基磷下游产品

三甲基磷制备

1、生产方法简介

由三氯化磷与甲基格利雅试剂反应制得。

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三甲基磷文献

Change of surface structure upon foam film formation.

ChemPhysChem 16(4) , 733-8, (2015)

The charge distribution and coverage with surfactant molecules at foam film surfaces plays an important role in determining foam film structure and stability. This work uses the concentration depth pr...

Molybdenum complex with bulky chelates as a functional model for molybdenum oxidases.

Inorg. Chem. 53(23) , 12416-27, (2014)

The novel bulky Schiff base chelate ligand [(4,5-diisopropyl-1H-pyrrole-2-yl)methylene]-4-(tert-butyl)aniline ((iPr2)HL) bearing two isopropyl groups close to the pyrrole nitrogen atom reacts with MoC...

Trimethylphosphine binding to horse-heart and sperm-whale myoglobins. Kinetics, proton magnetic resonance assignment and nuclear Overhauser effect investigation of the heme pocket.

Eur. J. Biochem. 214(2) , 405-14, (1993)

Two-dimensional nuclear magnetic resonance techniques have been used to assign resonances corresponding to the heme pocket and several other residues of horse heart and sperm whale myoglobins ligated ...

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