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邻硝基苯乙腈

邻硝基苯乙腈用途

【用途一】
用于制药

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邻硝基苯乙腈名称

[ CAS 号 ]:
610-66-2

[ 中文名 ]:
邻硝基苯乙腈

[ 英文名 ]:
2-Nitrophenylacetonitrile

[中文别名 ]:

[英文别名 ]:

MFCD00007183
2-(2-nitrophenyl)acetonitrile
EINECS 210-231-0

邻硝基苯乙腈物理化学性质

[ 密度 ]:
1.272 g/cm3

[ 沸点 ]:
178°C

[ 熔点 ]:
82-85 °C(lit.)

[ 分子式 ]:
C₈H₆N₂O₂

[ 分子量 ]:
162.14500

[ 闪点 ]:
138ºC

[ 精确质量 ]:
162.04300

[ PSA ]:
69.61000

[ LogP ]:
2.18408

[ 外观性状 ]:
淡棕色固体

[ 折射率 ]:
1.577

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

[ 水溶解性 ]:
<0.01 g/100 mL at 20 ºC

邻硝基苯乙腈MSDS

详细MSDS(安全技术说明书)

邻硝基苯乙腈毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AM1248000

CHEMICAL NAME :: Acetonitrile, (o-nitrophenyl)-

CAS REGISTRY NUMBER :: 610-66-2

BEILSTEIN REFERENCE NO. :: 1869400

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C8-H6-N2-O2

MOLECULAR WEIGHT :: 162.16

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 100 ug/plate

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 11(Suppl 12),1,1988

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邻硝基苯乙腈安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302 + H312 + H332-H315-H319-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R20/21/22

[ 安全声明 (欧洲) ]:
S26-S36-S24/25

[ 危险品运输编码 ]:
3439

[ WGK德国 ]:
3

[ RTECS号 ]:
AM1248000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2926909090

邻硝基苯乙腈海关

[ 海关编码 ]: 2926909090

[ 中文概述 ]:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

邻硝基苯乙腈文献

Enantioselective total synthesis of (-)-strychnine using the catalytic asymmetric Michael reaction and tandem cyclization.

J. Am. Chem. Soc. 124(49) , 14546-7, (2002)

The enantioselective total synthesis of (-)-strychnine was accomplished through the use of the highly practical catalytic asymmetric Michael reaction (0.1 mol % of (R)-ALB, more than kilogram scale, w...

Rapid access to α-carbolines via a one-pot tandem reaction of α,β-unsaturated ketones with 2-nitrophenylacetonitrile and the anti-proliferative activities of the products.

Org. Biomol. Chem. 12(2) , 355-61, (2014)

An effective and convenient method has been developed for the preparation of 2 or 2,4-substituted α-carbolines via a one-pot tandem reaction of α,β-unsaturated ketones with 2-nitrophenylacetonitrile i...

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