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邻氯氯苄

邻氯氯苄用途

【用途一】
用于生产邻氯氰苄、邻氯苯甲醇以及合成染料、制药等
【用途二】
邻氯氯苄是除草剂异恶草松的中间体，也是医药酶抑宁的中间体。
【用途三】
有机合成原料，医药工业用于制兴奋药酶抑宁等。

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邻氯氯苄名称

[ CAS 号 ]:
611-19-8

[ 中文名 ]:
邻氯氯苄

[ 英文名 ]:
o-Chlorobenzylchloride

[中文别名 ]:

[英文别名 ]:

Ortho-α-dichlorotoluene
Benzene, 1-chloro-2- (chloromethyl)-
2-chloromethylchlorobenzene
1-Chloro-2-(chloromethyl)benzene
,2-Dichlorotoluene
2-chloro-benzyl chloride
Toluene, o,α-dichloro-
α,o-Dichlorotoluene
A,O-DICHLOROTOLUENE
2-Chlorobenzyl chloride

邻氯氯苄物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
213.7±15.0 °C at 760 mmHg

[ 熔点 ]:
-13 °C

[ 分子式 ]:
C₇H₆Cl₂

[ 分子量 ]:
161.029

[ 闪点 ]:
82.2±0.0 °C

[ 精确质量 ]:
159.984650

[ LogP ]:
3.08

[ 外观性状 ]:
透明无色至淡黄色液体

[ 蒸汽密度 ]:
5.5 (vs air)

[ 蒸汽压 ]:
0.2±0.4 mmHg at 25°C

[ 折射率 ]:
1.547

[ 储存条件 ]:
库房低温通风干燥

[ 水溶解性 ]:
insoluble

邻氯氯苄MSDS

邻氯氯苄毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CZ0195000

CHEMICAL NAME :: Benzene, 1-chloro-2-(chloromethyl)-

CAS REGISTRY NUMBER :: 611-19-8

BEILSTEIN REFERENCE NO. :: 0471700

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C7-H6-Cl2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >1140 mg/m3/1H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0990-1020

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 430 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0990-1020 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84023 No. of Facilities: 5 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 20 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84023 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 4354 (estimated) No. of Female Employees: 729 (estimated)

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邻氯氯苄安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H317-H330

[ 警示性声明 ]:
P260-P280-P284-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R20/21/22;R34;R50/53

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S29

[ 危险品运输编码 ]:
UN 2235 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
CZ0195000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29036990

邻氯氯苄合成路线

邻氯氯苄上下游产品

邻氯氯苄上游产品

邻氯氯苄下游产品

邻氯氯苄制备

以邻甲苯胺为原料，经重氮化置换，氯化而得。将邻甲苯胺，盐酸，水混合，冷至0-5℃，将亚硝酸钠滴入，进行重氮化反应。在迅速搅拌下，于0℃倒入氯化亚铜，自然升温至20-25℃，最后升至60-65℃，保温20min后冷却，静置；分层；洗涤；蒸馏，得到邻氯甲苯。邻氯甲苯与三氯化磷混合，于130-140℃通氯，得邻氯氯苄。

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邻氯氯苄海关

[ 海关编码 ]: 29036990

邻氯氯苄文献

Computer-based bioassay for evaluation of sensory irritation of airborne chemicals and its limit of detection.

Arch. Toxicol. 72(5) , 277-82, (1998)

We expanded a previously described rule-based computerized method to recognize the sensory irritating effect of airborne chemicals. Using 2-chlorobenzylchloride (CBC) as a sensory irritant, characteri...

Computer assisted recognition and quantitation of the effects of airborne chemicals acting at different areas of the respiratory tract in mice.

Arch. Toxicol. 68(8) , 490-9, (1994)

The pattern and timing of a normal breath in unanesthetized mice was analyzed from measurement of inspiratory and expiratory airflows (VI and VE). Airflow was measured via a differential pressure tran...

Sterol-content lowering action of o-chlorobenzylchloride in yeast.

J. Biochem. 88(1) , 97-102, (1980)

o-Chlorobenzylchloride, a simple aromatic halogen compound, was found to inhibit the growth of Saccharomyces cerevisiae and to lower the contents of sterols and fatty acids. The growth inhibition was ...

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邻氯氯苄

邻氯氯苄用途

邻氯氯苄名称

邻氯氯苄物理化学性质

邻氯氯苄MSDS

详细MSDS(安全技术说明书)

邻氯氯苄毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

邻氯氯苄安全信息

邻氯氯苄合成路线

详细合成路线

邻氯氯苄上下游产品

邻氯氯苄上游产品

邻氯氯苄下游产品

邻氯氯苄制备

邻氯氯苄海关

邻氯氯苄文献

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