苯甲酰甲酸

Phenylglyoxylic acid (Benzoylformic acid) 是乙苯和苯乙烯 (EB/S) 的一种代谢物,可被用作人体暴露于 EB/S 的生物标志物。

[ 描述 ]:

[ 相关类别 ]:

[参考文献]

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
258.6±13.0 °C at 760 mmHg

[ 熔点 ]:
62-65 °C(lit.)

[ 分子式 ]:
C₈H₆O₃

[ 分子量 ]:
150.131

[ 闪点 ]:
124.4±16.3 °C

[ 精确质量 ]:
150.031693

[ PSA ]:
54.37000

[ LogP ]:
0.69

[ 外观性状 ]:
淡黄色固体

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.569

[ 储存条件 ]:
Refrigerator

[ 水溶解性 ]:
methanol: 0.1 g/mL, clear

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

DA1480000

CHEMICAL NAME :

Benzeneglyoxylic acid

CAS REGISTRY NUMBER :

611-73-4

BEILSTEIN REFERENCE NO. :

0606718

LAST UPDATED :

199709

DATA ITEMS CITED :

1

MOLECULAR FORMULA :

C8-H6-O3

MOLECULAR WEIGHT :

150.14

WISWESSER LINE NOTATION :

QVVR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intravenous

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

180 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04110

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S28-S36-S28A-S24-S22

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
DA1480000

[ 海关编码 ]:
29183000

详细合成路线

苯甲酰甲酸上游产品

苯甲酰甲酸下游产品

由苯甲酰氰用浓盐酸水解而得。

[ 海关编码 ]: 2918300090

[ 中文概述 ]:
2918300090 其他含醛基或酮基不含其他含氧基羧酸（包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Development of a multi-residue method in a fetal matrix: analysis of meconium.

Anal. Bioanal. Chem 406(30) , 7785-97, (2014)

Meconium is the earliest stool of newborns. It is a complex matrix that reflects the degree of fetal exposure to environmental pollutants. To investigate exposure to xenobiotics, an analytical method ...

Development of liquid chromatography methods coupled to mass spectrometry for the analysis of substances with a wide variety of polarity in meconium.

Talanta 138 , 231-9, (2015)

Meconium is the first fecal excretion of newborns. This complex accumulative matrix allows assessing the exposure of the fetus to xenobiotics during the last 6 months of pregnancy. To determine the ev...

Copper/alpha-ketocarboxylate chemistry with supporting peralkylated diamines: reactivity of copper(I) complexes and dicopper-oxygen intermediates.

Inorg. Chem. 49(7) , 3531-9, (2010)

To further understand copper-promoted oxidation reactions, the Cu(I) complexes LCuX (L = N,N'-di-tert-butyl-N,N'-dimethylethylenediamine; X = benzoylformate (BF) or p-nitro-benzoylformate) were synthe...

更多文献

公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：苯甲酰甲酸

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公司名：南通润丰石油化工有限公司

区域：南通市崇川区

价格：
￥需询单/1kg ￥需询单/1ton

联系人：曹经理

产品详情：苯甲酰甲酸

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥318.0/25g ￥108.0/5g

联系人：刘佳

产品详情：苯甲酰甲酸

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥29.9/1g ￥205.9/1ml ￥240.9/25g ￥3124.9/500g

联系人：阿拉丁

产品详情：苯甲酰甲酸

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公司名：上海创赛科技有限公司

区域：上海市嘉定区

价格：
￥35.0/1g ￥75.0/5g ￥240.0/25g ￥820.0/100g

联系人：夏言

产品详情：[Perfemiker]苯甲酰甲酸,>95.0%(GC)

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