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对硝基苯甲酰胺

对硝基苯甲酰胺用途

【用途一】
用作医药、染料中间体

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对硝基苯甲酰胺名称

[ CAS 号 ]:
619-80-7

[ 中文名 ]:
对硝基苯甲酰胺

[ 英文名 ]:
4-Nitrobenzamide

[中文别名 ]:

4-硝基苯甲酰胺

[英文别名 ]:

4-Nitrobenzamide
Benzamide, 4-nitro-
EINECS 210-613-7
4-Nitrobenzolcarboxamid
4-Nitrophenylformamide
MFCD00007994

对硝基苯甲酰胺物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
368.0±25.0 °C at 760 mmHg

[ 熔点 ]:
199-201 °C(lit.)

[ 分子式 ]:
C₇H₆N₂O₃

[ 分子量 ]:
166.134

[ 闪点 ]:
176.3±23.2 °C

[ 精确质量 ]:
166.037842

[ PSA ]:
88.91000

[ LogP ]:
0.82

[ 外观性状 ]:
淡黄色粉末

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.612

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、食品添加剂分开存放

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents, strong bases.

[ 水溶解性 ]:
<0.01 g/100 mL at 18 ºC

对硝基苯甲酰胺MSDS

对硝基苯甲酰胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CV5601000

CHEMICAL NAME :: Benzamide, p-nitro-

CAS REGISTRY NUMBER :: 619-80-7

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C7-H6-N2-O3

MOLECULAR WEIGHT :: 166.15

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - guinea pig

REFERENCE :: EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0183-0462 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 476 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0183-0462

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,53,1954

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 28,335,1994

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对硝基苯甲酰胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302

[ 警示性声明 ]:
P301 + P312 + P330

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S27-S28-S36/37/39-S45

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
CV5601000

[ 海关编码 ]:
2924299090

对硝基苯甲酰胺合成路线

对硝基苯甲酰胺上下游产品

对硝基苯甲酰胺上游产品

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对硝基苯甲酰胺海关

[ 海关编码 ]: 2924299090

[ 中文概述 ]:
2924299090. 其他环酰胺（包括环氨基甲酸酯）（包括其衍生物以及他们的盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

对硝基苯甲酰胺文献

Observation of amide anions in solution by electrospray ionization mass spectrometry.

J. Am. Soc. Mass Spectrom. 11(12) , 1061-4, (2000)

Negative quasimolecular ions of aromatic carboxylic acid amides have been observed unexpectedly under electrospray ionization conditions. Hypothetically, deprotonation of either carboxamide or carboxi...

Preparation of nitriles from primary amides under Swern oxidation conditions. Nakajima N and Ubukata M.

Tetrahedron Lett. 38(12) , 2099-2102, (1997)

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