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2,4-戊二醇

2,4-戊二醇用途

用作有机合成原料及光学活性试剂。

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2,4-戊二醇名称

[ CAS 号 ]:
625-69-4

[ 中文名 ]:
2,4-戊二醇

[ 英文名 ]:
2,4-PENTANEDIOL

[中文别名 ]:

[英文别名 ]:

2,4-戊二醇物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
199.5±0.0 °C at 760 mmHg

[ 分子式 ]:
C5H12O2

[ 分子量 ]:
104.148

[ 闪点 ]:
101.7±0.0 °C

[ 精确质量 ]:
104.083733

[ PSA ]:
40.46000

[ LogP ]:
-0.34

[ 外观性状 ]:
透明无色至略淡黄色液体

[ 蒸汽压 ]:
0.1±0.8 mmHg at 25°C

[ 折射率 ]:
1.441

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (吸湿)

2,4-戊二醇MSDS

2,4-戊二醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SA0490000
CHEMICAL NAME :
2,4-Pentanediol
CAS REGISTRY NUMBER :
625-69-4
LAST UPDATED :
199806
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C5-H12-O2
MOLECULAR WEIGHT :
104.17
WISWESSER LINE NOTATION :
QY&1YQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,209,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6860 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5792 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JAPMA8 Journal of the American Pharmaceutical Association, Scientific Edition. (Washington, DC) V.29-49, 1940-60. For publisher information, see JPMSAE. Volume(issue)/page/year: 45,669,1956
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
14100 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0865 No. of Facilities: 379 (estimated) No. of Industries: 12 No. of Occupations: 12 No. of Employees: 3899 (estimated)
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2,4-戊二醇安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 安全声明 (欧洲) ]:
24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
SA0490000

2,4-戊二醇制备

由乙酰丙酮用兰尼镍(Raney-Ni)催化加氢制得。

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2,4-戊二醇文献

Brønsted acid catalyzed asymmetric reduction of ketones and acyl silanes using chiral anti-pentane-2,4-diol.

Org. Lett. 12(10) , 2294-7, (2010)

Ketones and acyl silanes were reduced to the corresponding alcohols by a simple procedure employing anti-1,3-diol and a catalytic amount (5 mol %) of 2,4-dinitrobenzenesulfonic acid in benzene at refl...

Highly efficient synthesis of enantiopure diacetylated C(2)-symmetric diols by ruthenium- and enzyme-catalyzed dynamic kinetic asymmetric transformation (DYKAT).

Chemistry 12 , 6053, (2006)

Highly efficient synthesis of enantiopure diacetates of 2,4-pentanediol and 2,5-hexanediol starting from commercially available mixtures of the diols (dl/meso approximately 1:1) has been realized by c...

2,4-Pentanediolate as an alkoxide/diketonate "hybrid" ligand and the formation of aluminum and zirconium derivatives.

Inorg. Chem. 50(23) , 12126-32, (2011)

When 2,4-pentanediol (2,4-H(2)pd) is deprotonated, the resulting dianion (2,4-pd) serves as a type of "hybrid" ligand, i.e., an alkoxide that possesses structural features of a β-diketonate. 2,4-Penta...


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区域:上海市嘉定区

价格:
¥231.0/5g

联系人:夏言

产品详情:[Perfemiker]2,4-戊二醇,≥98%


公司名:上海阿拉丁生化科技股份有限公司

区域:上海市浦东新区

价格:
¥119.0/5g ¥4899.0/25g ¥需询单/1g ¥1559.0/100g

联系人:阿拉丁

产品详情:2,4-戊二醇


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标题:2,4-戊二醇_MSDS_用途_密度_CAS号【625-69-4】_化源网 地址:https://m.chemsrc.com/mip/cas/625-69-4_449012.html