< 生产厂家价格 >

2-己醇

2-己醇用途

1.用作溶剂和乳化剂。也可用来制己二酸、增塑剂、洗涤剂等。

2.用作溶剂。

点击显示

2-己醇名称

[ CAS 号 ]:
626-93-7

[ 中文名 ]:
2-己醇

[ 英文名 ]:
2-Hexanol

[中文别名 ]:

[英文别名 ]:

methyl-n-amyl-carbinol
(RS)-2-hexanol
cis-2-hexan-1-ol
Methylpentanol
trans-2-hexanol
Hexan-2-ol
n-butyl methyl carbinol
5-hexane-1-ol
methyl-hexanol
EINECS 210-971-4

2-己醇物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
139.7±3.0 °C at 760 mmHg

[ 熔点 ]:
-23ºC

[ 分子式 ]:
C₆H₁₄O

[ 分子量 ]:
102.175

[ 闪点 ]:
46.1±0.0 °C

[ 精确质量 ]:
102.104462

[ PSA ]:
20.23000

[ LogP ]:
1.75

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
2.6±0.5 mmHg at 25°C

[ 折射率 ]:
1.414

[ 储存条件 ]:
Flammables area

[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents. Mixtures with air may be explosive.

2-己醇MSDS

2-己醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MO8470000

CHEMICAL NAME :: 2-Hexanol

CAS REGISTRY NUMBER :: 626-93-7

BEILSTEIN REFERENCE NO. :: 1718996

LAST UPDATED :: 199710

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C6-H14-O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 24895 mg/kg/34W-I

TOXIC EFFECTS :: Peripheral Nerve and Sensation - sensory change involving peripheral nerve Peripheral Nerve and Sensation - recording from peripheral motor nerve

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 46,421,1978

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 78926 mg/kg/24W-C

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - miosis (pupillary constriction) Behavioral - somnolence (general depressed activity) Nutritional and Gross Metabolic - other changes

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 39,94,1978

点击显示

2-己醇安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn,Xi

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S16

[ 危险品运输编码 ]:
UN 2282 3/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
MO8470000

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

2-己醇合成路线

2-己醇上下游产品

2-己醇上游产品

2-己醇下游产品

2-己醇制备

1.制法：

于装有搅拌器、滴液漏斗、温度计的反应瓶中，加入醋酸汞31.9g(0.1mol),水100mL，搅拌使醋酸汞溶解，加入100mL四氢呋喃，立即生成橙黄色。搅拌15min后，加入1-己烯(2)8.5g（0.1mol），室温搅拌反应1h，以使羟汞化完全。剧烈搅拌下加入3mol/L的氢氧化钠溶液100mL，滴加由硼氢化钠1.9g(0.05mol)溶于100mL3mol/L的氢氧化钠配成的溶液，滴加速度控制反应液温度25℃左右。必要时可用水浴冷却。反应中迅速生成元素汞。室温剧烈搅拌反应3h，于分液漏斗中放置过夜。分出汞(19.25g,96%)和水，保留有机层。水层用氯化钠饱和，乙醚提取(3mL×2),合并有机层，减压蒸出溶剂，当出现两相时停止蒸馏。加入50mL乙醚和20mL水。分出乙醚层，水洗四次，无水磷酸钙干燥。先蒸出乙醚，剩余物继续蒸馏，收集136～140℃的馏分，得2-己醇（1）6.9g，收率68%。

点击显示

2-己醇文献

Convenient QSAR model for predicting the complexation of structurally diverse compounds with β-cyclodextrins

Bioorg. Med. Chem. 17 , 896-904, (2009)

This paper reports a QSAR study for predicting the complexation of a large and heterogeneous variety of substances (233 organic compounds) with beta-cyclodextrins (beta-CDs). Several different theoret...

Changes of n-hexane metabolites in urine of rats exposed to various concentrations of n-hexane and to its mixture with toluene or MEK.

Int. Arch. Occup. Environ. Health 53(1) , 1-8, (1983)

It is well known that n-hexane produces peripheral neuropathy, and 2,5-hexanedione, one of the metabolites of n-hexane, is thought to be the main causative agent. Recently, the metabolites of n-hexane...

Two-chiral-component microemulsion electrokinetic chromatography-chiral surfactant and chiral oil: part 1. dibutyl tartrate.

Electrophoresis 28(11) , 1723-34, (2007)

The first simultaneous use of a chiral surfactant and a chiral oil for microemulsion EKC (MEEKC) is reported. Six stereochemical combinations of dodecoxycarbonylvaline (DDCV: R, S, or racemic, 2.00% w...

更多文献

2-己醇

2-己醇用途

2-己醇名称

2-己醇物理化学性质

2-己醇MSDS

详细MSDS(安全技术说明书)

2-己醇毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

2-己醇安全信息

2-己醇合成路线

详细合成路线

2-己醇上下游产品

2-己醇上游产品

2-己醇下游产品

2-己醇制备

2-己醇文献

相关化工产品/化学物质：

推荐生产厂家/供应商：

相关化合物