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氟酰胺

氟酰胺用途

属苯甲酰胺衍生物，具有预防和治疗作用的内吸性杀菌剂。用于防治某些担子菌纲真菌。对菌丝的生育和侵入菌丝块的形成具有很强的阻碍作用。如防治丝核菌引起的水稻纹枯病，以50mg/L浓度茎叶处理，防治效果100%。
用途 内吸杀菌剂，对水稻纹枯病，马铃薯黑痣病等有效。
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氟酰胺名称

[ CAS 号 ]:
66332-96-5

[ 中文名 ]:
氟酰胺

[ 英文名 ]:
FLUTOLANIL

[中文别名 ]:

[英文别名 ]:

氟酰胺物理化学性质

[ 密度 ]:
1.247g/cm3

[ 沸点 ]:
339.1ºC at 760 mmHg

[ 熔点 ]:
108° (Araki, Yabutani); mp 104-105° (Araki, 1985)

[ 分子式 ]:
C17H16F3NO2

[ 分子量 ]:
323.31000

[ 闪点 ]:
158.9ºC

[ 精确质量 ]:
323.11300

[ PSA ]:
38.33000

[ LogP ]:
4.81790

[ 折射率 ]:
1.543

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

氟酰胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CV5581320
CHEMICAL NAME :
Benzamide, N-(3-(1-methylethoxy)phenyl)-2-(trifluoromethyl)-
CAS REGISTRY NUMBER :
66332-96-5
LAST UPDATED :
199701
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C17-H16-F3-N-O2
MOLECULAR WEIGHT :
323.34

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C209,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (47),23,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 13,153,1988
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 13,153,1988
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,426,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 13,153,1988
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 13,153,1988 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
18 gm/kg/30D-C
TOXIC EFFECTS :
Liver - other changes Liver - changes in liver weight Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 13,153,1988
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
438 gm/kg/2Y-C
TOXIC EFFECTS :
Liver - other changes Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 13,153,1988
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
913 gm/kg/2Y-I
TOXIC EFFECTS :
Gastrointestinal - ulceration or bleeding from duodenum Gastrointestinal - nausea or vomiting Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 13,153,1988
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氟酰胺安全信息

[ 危害码 (欧洲) ]:
F+

[ RTECS号 ]:
CV5581320

[ 危险类别 ]:
3，6.1

[ 海关编码 ]:
2924299033

氟酰胺合成路线

详细合成路线

氟酰胺上下游产品

氟酰胺上游产品

氟酰胺下游产品

氟酰胺制备

制备方法一
邻三氟甲基苯甲酰氯可用邻三氟甲基氯苯为原料，经过格氏反应，然后与干冰反应羰基化，再经水解得邻三氟甲基苯甲酸，该酸经酰氯化制得邻三氟甲基苯甲酰氯。邻三氟甲基苯甲酰氯在冰冷却下，加到四氢呋喃中，在三乙胺存下及室温下，与间异丙氧基苯胺反应2h，得氟担菌宁。
制备方法二
氟担菌宁也可通过3-（2-三氟甲基苯甲酰氨基）苯酚与2-氯代丙烷反应制得。
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氟酰胺海关

[ 海关编码 ]: 2924299033

[ 中文概述 ]:
2924299033 庚酰草胺、环丙草胺、环酰草胺、氟虫隆等〔包括氟虫脲、氟铃脲、氟酰胺、氟蚁灵、氟幼脲〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2924299033 2,6-difluoro-n-((4-(trifluoromethyl)phenyl)carbamoyl)benzamide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

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推荐生产厂家/供应商：

公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：氟酰胺

公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥538.0/100mg

联系人：刘佳

产品详情：氟酰胺

公司名：上海脉铂医药科技有限公司

区域：上海市嘉定区

价格：
￥640.0/50mg ￥918.0/100mg ￥需询单/1g ￥需询单/1g

联系人：李先生

产品详情：Flutolanil

公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥513.9/100mg ￥需询单/1g ￥需询单/1g ￥需询单/1g

联系人：阿拉丁

产品详情：氟酰胺

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